Microwave-assisted synthesis of corroles

被引:51
作者
Collman, JP [1 ]
Decréau, RA [1 ]
机构
[1] Stanford Univ, Dept Chem, Stanford, CA 94305 USA
关键词
corrole synthesis; microwave irradiation;
D O I
10.1016/S0040-4039(02)02792-2
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The recently developed Gross's method for the synthesis of corroles has been modified and successfully applied to the preparation of new free base tris-aryl- and tris-pyrimidyl-corroles using solvent-free conditions and microwave irradiation. Compared to conventional heating, the microwave technique afforded an increase in corrole yields of ca. 30% and led to noticeably cleaner reaction mixtures. It is demonstrated that short reaction times and high temperatures are required to afford optimum yields. (C) 2003 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1207 / 1210
页数:4
相关论文
共 31 条
  • [1] Sterically encumbered triarylcorroles from aryldipyrromethanes and aromatic aldehydes
    Asokan, CV
    Smeets, S
    Dehaen, W
    [J]. TETRAHEDRON LETTERS, 2001, 42 (27) : 4483 - 4485
  • [2] Aviezer D, 2000, CANCER RES, V60, P2973
  • [3] SYNTHESEN IN DER HETEROCYCLISCHEN REIHE .9. SYNTHESEN UND REAKTIONEN VON 4.6-DISUBSTITUIERTEN PYRIMIDIN-ALDEHYDEN-(5)
    BREDERECK, H
    SIMCHEN, G
    SANTOS, AA
    [J]. CHEMISCHE BERICHTE-RECUEIL, 1967, 100 (04): : 1344 - +
  • [4] MICROWAVE-ASSISTED ORGANIC-REACTIONS
    CADDICK, S
    [J]. TETRAHEDRON, 1995, 51 (38) : 10403 - 10432
  • [5] Microwave-assisted synthesis of 5,10,15,20-tetraaryl porphyrins
    Chauhan, SMS
    Sahoo, BB
    Srinivas, KA
    [J]. SYNTHETIC COMMUNICATIONS, 2001, 31 (01) : 33 - 37
  • [6] First catalysis by corrole metal complexes: epoxidation, hydroxylation, and cyclopropanation
    Gross, Z
    Simkhovich, L
    Galili, N
    [J]. CHEMICAL COMMUNICATIONS, 1999, (07) : 599 - 600
  • [7] Gross Z, 2000, ANGEW CHEM INT EDIT, V39, P4045, DOI 10.1002/1521-3773(20001117)39:22<4045::AID-ANIE4045>3.0.CO
  • [8] 2-P
  • [9] Solvent-free condensation of pyrrole and pentafluorobenzaldehyde:: A novel synthetic pathway to corrole and oligopyrromethenes
    Gross, Z
    Galili, N
    Simkhovich, L
    Saltsman, I
    Botoshansky, M
    Bläser, D
    Boese, R
    Goldberg, I
    [J]. ORGANIC LETTERS, 1999, 1 (04) : 599 - 602
  • [10] Gross Z, 1999, ANGEW CHEM INT EDIT, V38, P1427, DOI 10.1002/(SICI)1521-3773(19990517)38:10<1427::AID-ANIE1427>3.0.CO