Microwave-assisted synthesis of corroles

被引：51

作者：

Collman, JP ^{[1
]}

Decréau, RA ^{[1
]}

机构：

[1] Stanford Univ, Dept Chem, Stanford, CA 94305 USA

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 06期

关键词：

corrole synthesis; microwave irradiation;

D O I：

10.1016/S0040-4039(02)02792-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The recently developed Gross's method for the synthesis of corroles has been modified and successfully applied to the preparation of new free base tris-aryl- and tris-pyrimidyl-corroles using solvent-free conditions and microwave irradiation. Compared to conventional heating, the microwave technique afforded an increase in corrole yields of ca. 30% and led to noticeably cleaner reaction mixtures. It is demonstrated that short reaction times and high temperatures are required to afford optimum yields. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：1207 / 1210

页数：4

共 31 条

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