First catalysis by corrole metal complexes: epoxidation, hydroxylation, and cyclopropanation

被引：185

作者：

Gross, Z ^{[1
]}

Simkhovich, L ^{[1
]}

Galili, N ^{[1
]}

机构：

[1] Technion Israel Inst Technol, Dept Chem, IL-32000 Haifa, Israel

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 07期

关键词：

D O I：

10.1039/a900571d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first ever application of corroles shows that their metal complexes are good catalysts, almost as potent as the corresponding metalloporphyrins in the oxygenation of hydrocarbons by iodosylbenzene and superior for the cyclopropanation of olefins by carbenoids.

引用

页码：599 / 600

页数：2

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