Fe3O4 submicron spheroids as anode materials for lithium-ion batteries with stable and high electrochemical performance

被引:177
作者
Wang, Suqing [1 ]
Zhang, Jingying [1 ]
Chen, Chunhua [1 ]
机构
[1] Univ Sci & Technol China, Dept Mat Sci & Engn, CAS Key Lab Mat Energy Convers, Hefei 230026, Anhui, Peoples R China
基金
美国国家科学基金会;
关键词
Magnetite; Microsphere; Hydrothermal; Lithium battery; Electrode; ELECTRODE; NANOCRYSTALS;
D O I
10.1016/j.jpowsour.2010.03.035
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A magnetite (Fe3O4) powder composed of uniform sub-micrometer spherical particles has been successfully synthesized by a hydrothermal method at low temperature. X-ray diffraction, scanning electron microscopy, transmission electron microscopy and galvanostatic cell cycling are employed to characterize the structure and electrochemical performance of the as-prepared Fe3O4 spheroids. The magnetite shows a stable and reversible capacity of over 900 mAh g(-1) during up to 60 cycles and good rate capability. The experimental results suggest that the Fe3O4 synthesized by this method is a promising anode material for high energy-density lithium-ion batteries. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:5379 / 5381
页数:3
相关论文
共 19 条
[1]   High-Yield Gas-Liquid Interfacial Synthesis of Highly Dispersed Fe3O4 Nanocrystals and Their Application in Lithium-Ion Batteries [J].
Cui, Zhi-Min ;
Hang, Ling-Yan ;
Song, Wei-Guo ;
Guo, Yu-Guo .
CHEMISTRY OF MATERIALS, 2009, 21 (06) :1162-1166
[2]   Monodisperse magnetic single-crystal ferrite microspheres [J].
Deng, H ;
Li, XL ;
Peng, Q ;
Wang, X ;
Chen, JP ;
Li, YD .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (18) :2782-2785
[3]   Fabrication and characterization of Fe3O4-based Cu nanostructured electrode for Li-ion battery [J].
Duan, Huanan ;
Gnanaraj, Joe ;
Chen, Xiangping ;
Li, Boquan ;
Liang, Jianyu .
JOURNAL OF POWER SOURCES, 2008, 185 (01) :512-518
[4]   Preparation of biocompatible magnetite nanocrystals for in vivo magnetic resonance detection of cancer [J].
Hu, Fengqin ;
Wei, Li ;
Zhou, Zhuan ;
Ran, Yuliang ;
Li, Zhen ;
Gao, Mingyuan .
ADVANCED MATERIALS, 2006, 18 (19) :2553-+
[5]   Lithium battery having a large capacity using Fe3O4 as a cathode material [J].
Ito, S ;
Nakaoka, K ;
Kawamura, A ;
Ui, K ;
Fujimoto, K ;
Koura, N .
JOURNAL OF POWER SOURCES, 2005, 146 (1-2) :319-322
[6]   On the origin of the extra electrochemical capacity displayed by MO/Li cells at low potential [J].
Laruelle, S ;
Grugeon, S ;
Poizot, P ;
Dollé, M ;
Dupont, L ;
Tarascon, JM .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2002, 149 (05) :A627-A634
[7]   Enhanced cycling performance of an Fe0/Fe3O4 nanocomposite electrode for lithium-ion batteries [J].
Lee, Gwang-Hee ;
Park, Jae-Gwan ;
Sung, Yun-Mo ;
Chung, Kyung Yoon ;
Cho, Won Il ;
Kim, Dong-Wan .
NANOTECHNOLOGY, 2009, 20 (29)
[8]   Li-storage via heterogeneous reaction in selected binary metal fluorides and oxides [J].
Li, H ;
Balaya, P ;
Maier, J .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (11) :A1878-A1885
[9]   Magnetite/carbon core-shell nanorods as anode materials for lithium-ion batteries [J].
Liu, Hao ;
Wang, Guoxiu ;
Wang, Jiazhao ;
Wexler, David .
ELECTROCHEMISTRY COMMUNICATIONS, 2008, 10 (12) :1879-1882
[10]   Nano-sized transition-metaloxides as negative-electrode materials for lithium-ion batteries [J].
Poizot, P ;
Laruelle, S ;
Grugeon, S ;
Dupont, L ;
Tarascon, JM .
NATURE, 2000, 407 (6803) :496-499