A novel 2:1 supramolecular assembly of 3,5-dinitrobenzoic acid and 1,4-diiodobenzene

被引:32
作者
Ranganathan, A [1 ]
Pedireddi, VR [1 ]
机构
[1] Indian Inst Sci, Jawaharlal Nehru Ctr Adv Sci Res, Chem & Phys Mat Unit, Bangalore 560064, Karnataka, India
关键词
D O I
10.1016/S0040-4039(98)00092-6
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
3,5-Dinitrobenzoic acid, 1, forms a 2:1 molecular complex with 1,4-diiodobenzene, 2, through the formation of iodo-nitro interactions utilising one of its nitro groups, rather than forming a 1:1 molecular complex using both the nitro groups. The result suggests the importance of the hydrogen bond interactions present in the crystal of the parent molecule (1) in directing the interaction with Other donor molecules (2). (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1803 / 1806
页数:4
相关论文
共 12 条
[11]  
VOGTLE F, 1971, SUPRAMOLECULAR CHEM
[12]   NONCOVALENT SYNTHESIS - USING PHYSICAL-ORGANIC CHEMISTRY TO MAKE AGGREGATES [J].
WHITESIDES, GM ;
SIMANEK, EE ;
MATHIAS, JP ;
SETO, CT ;
CHIN, DN ;
MAMMEN, M ;
GORDON, DM .
ACCOUNTS OF CHEMICAL RESEARCH, 1995, 28 (01) :37-44