Novel octanuclear and enneanuclear manganese clusters with carboxylate and pyrimidine ligands

被引:24
作者
Brechin, EK
Christou, G
Soler, M
Helliwell, M
Teat, SJ
机构
[1] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England
[2] Univ Florida, Dept Chem, Gainesville, FL 32611 USA
[3] CLRC, Daresbury Lab, Warrington WA4 4AD, Cheshire, England
关键词
D O I
10.1039/b212347a
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The syntheses, structures and initial magnetic properties of three new high nuclearity manganese clusters containing new topologies of metal ions are reported.
引用
收藏
页码:513 / 514
页数:2
相关论文
共 13 条
[1]   Single-molecule magnet behavior of a tetranuclear iron(III) complex. The origin of slow magnetic relaxation in iron(III) clusters [J].
Barra, AL ;
Caneschi, A ;
Cornia, A ;
de Biani, FF ;
Gatteschi, D ;
Sangregorio, C ;
Sessoli, R ;
Sorace, L .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (22) :5302-5310
[2]   Single-molecule magnets:: A new family of Mn12 clusters of formula [Mn12O8X4(O2CPh)8L6] [J].
Boskovic, C ;
Brechin, EK ;
Streib, WE ;
Folting, K ;
Bollinger, JC ;
Hendrickson, DN ;
Christou, G .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (14) :3725-3736
[3]   A new class of single-molecule magnet:: [Mn9O7(OAc)11(thme)(py)3(H2O)2] with an S=17/2 ground state [J].
Brechin, EK ;
Soler, M ;
Davidson, J ;
Hendrickson, DN ;
Parsons, S ;
Christou, G .
CHEMICAL COMMUNICATIONS, 2002, (19) :2252-2253
[4]   Quantum tunneling of magnetization in a new [Mn18]2+ single-molecule magnet with S=13 [J].
Brechin, EK ;
Boskovic, C ;
Wernsdorfer, W ;
Yoo, J ;
Yamaguchi, A ;
Sañudo, EC ;
Concolino, TR ;
Rheingold, AL ;
Ishimoto, H ;
Hendrickson, DN ;
Christou, G .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (33) :9710-9711
[5]   Studies of a nickel-based single molecule magnet:: resonant quantum tunnelling in an S=12 molecule [J].
Cadiou, C ;
Murrie, M ;
Paulsen, C ;
Villar, V ;
Wernsdorfer, W ;
Winpenny, REP .
CHEMICAL COMMUNICATIONS, 2001, (24) :2666-2667
[6]   Single-molecule magnets [J].
Christou, George ;
Gatteschi, Dante ;
Hendrickson, David N. ;
Sessoli, Roberta .
MRS Bulletin, 2000, 25 (11) :66-71
[7]   Magnetization tunneling in single-molecule magnets [J].
Hendrickson, DN ;
Christou, G ;
Ishimoto, H ;
Yoo, J ;
Brechin, EK ;
Yamaguchi, A ;
Rumberger, EM ;
Aubin, SMJ ;
Sun, ZM ;
Aromí, G .
POLYHEDRON, 2001, 20 (11-14) :1479-1488
[8]  
LOW DW, 1991, INORG CHEM, V30, P878
[9]   Quantum tunneling of the magnetization in an iron cluster nanomagnet [J].
Sangregorio, C ;
Ohm, T ;
Paulsen, C ;
Sessoli, R ;
Gatteschi, D .
PHYSICAL REVIEW LETTERS, 1997, 78 (24) :4645-4648
[10]   MAGNETIC BISTABILITY IN A METAL-ION CLUSTER [J].
SESSOLI, R ;
GATTESCHI, D ;
CANESCHI, A ;
NOVAK, MA .
NATURE, 1993, 365 (6442) :141-143