Structural authentication of an N-functionalised disecondary diphosphane

被引:9
作者
Andrews, PC [1 ]
King, SJ [1 ]
Raston, CL [1 ]
Roberts, BA [1 ]
机构
[1] Monash Univ, Dept Chem, Clayton, Vic 3168, Australia
关键词
D O I
10.1039/a706481k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The reaction of RPCl2 [R = (6-Me-2-pyridyl)(SiMe3)(2)C-] with LiAlH4 in Et2O gives the novel N-functionalised disecondary diphosphane compound [ROT)P-P(H)R] rather than the expected phosphorus dihydride complex RPH2; the meso and rac isomers of the diphosphane crystallise separately with the meso isomer being structurally authenticated.
引用
收藏
页码:547 / 548
页数:2
相关论文
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