A high-mobility electron-transport polymer with broad absorption and its use in field-effect transistors and all-polymer solar cells

被引：1101

作者：

Zhan, Xiaowei ^{[1
]}

Tan, Zhan'ao

Domercq, Benoit

An, Zesheng

Zhang, Xuan

Barlow, Stephen

Li, Yongfang

Zhu, Daoben

Kippelen, Bernard

Marder, Seth R.

机构：

[1] Chinese Acad Sci, Inst Chem, Nat Lab, Beijing 100080, Peoples R China

[2] Chinese Acad Sci, Inst Chem, Key Lab Organ Solids, Beijing 100080, Peoples R China

[3] Georgia Inst Technol, Sch Chem & Biochem, Ctr Organ Photon & Electron, Atlanta, GA 30332 USA

[4] Georgia Inst Technol, Sch Elect & Comp Engn, Ctr Organ Photon & Electron, Atlanta, GA 30332 USA

[5] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 23期

关键词：

D O I：

10.1021/ja071760d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An electron-transport polymer with good solution processibility, excellent thermal stability, and high electron affinity based on alternating perylene diimide and dithienothiophene units has been synthesized. Electron mobilities as high as 1.3 x 10(-2) cm(2) V-1 s(-1) have been measured in field-effect transistor geometry. The polymer shows broad absorptions throughout the visible and extending into the near-IR. A power conversion efficiency of over 1%, under simulated AM 1.5, 100 mW/cm(2), was measured for a single-layer solar cell using this polymer as an acceptor and a polythiophene derivative as a donor.

引用

页码：7246 / +

页数：3

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