Spray-Processable Blue-to-Highly Transmissive Switching Polymer Electrochromes via the Donor-Acceptor Approach

被引：136

作者：

Amb, Chad M. ^{[1
]}

Beaujuge, Pierre M. ^{[1
]}

Reynolds, John R. ^{[1
]}

机构：

[1] Univ Florida, Ctr Macromol Sci & Engn, Dept Chem, George & Josephine Butler Polymer Res Lab, Gainesville, FL 32611 USA

来源：

ADVANCED MATERIALS | 2010年 / 22卷 / 06期

关键词：

DESIGNING SYNTHETIC METALS; HIGH-CONTRAST; BAND-GAP; CONJUGATED POLYMERS; CHARGE-TRANSPORT; CONCEPT WORK; GREEN; BENZOTHIADIAZOLE; PHOTOPHYSICS; PERFORMANCE;

D O I：

10.1002/adma.200902917

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Spray processable blue electrochromic polymers with strictly alternating "donor-acceptor" copolymers are reported that exhibit saturated blue neutral states, highly transmissive oxidized states excellent optical contrasts, fast switching times, and long-term redox switching stability. In addition, an alkylester-functionalized analogue is demonstrated, where the solubility of the material thin-film is irreversibly changed while allowing it to retain its electroactivity.

引用

收藏

页码：724 / +

页数：6

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