Successive O-C/O-H and sp3 C-H bond activation of ortho substituents in allyl phenyl ethers and phenols by a Ruthenium(0) complex

被引：33

作者：

Hirano, M ^{[1
]}

Kurata, N ^{[1
]}

Marumo, T ^{[1
]}

Komiya, S ^{[1
]}

机构：

[1] Tokyo Univ Agr & Technol, Fac Technol, Dept Appl Chem, Tokyo 1848588, Japan

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 04期

关键词：

D O I：

10.1021/om970911q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Successive O-C and sp(3) C-H bond activation. occurs in the reaction of Ru(COD)(COT) (1) [PMe3 with allyl 2,6-xylyl ether to give Ru[OC6H3(o-CH2)(o'-Me)](PMe3)(4) (4). Alternatively, 4 can be obtained by O-H and sp(3) C-H bond activation in 2,6-xylenol by 1/PMe3. In both cases, an eta(3)-allyl fragment could be responsible for the sp(3) C-H bond activation.

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收藏

页码：501 / 503

页数：3

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