Formation of multi-shelled carbon nanoparticles by arc discharge in liquid benzene

被引：51

作者：

Sano, N ^{[1
]}

机构：

[1] Univ Hyogo, Himeji Inst Technol, Grad Sch Mech Syst Engn, Himeji, Hyogo 6712201, Japan

来源：

MATERIALS CHEMISTRY AND PHYSICS | 2004年 / 88卷 / 2-3期

基金：

日本学术振兴会;

关键词：

fullerenes; multi-shelled nanoparticles; nanostructures; arc discharges; electron microscopy;

D O I：

10.1016/j.matchemphys.2004.07.018

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

'Arc in liquid' method is a cost-effective technique lately proposed to fabricate carbon nanomaterials, which does not require vacuum facilities. Currently, it is demanded to examine the effect of liquid components on the products synthesized by this method. In this study, liquid benzene (C6H6) was used in the 'arc in liquid' method. As a result, multi-shelled nanoparticles of diameter 10-30 nm were found in the deposits formed between electrodes, in which highly curled graphitic structure seemed majority. Importantly, CNTs are not formed in this condition, which is different from arc in water or liquid nitrogen. In addition, it was confirmed that fullerene was not produced by the present condition. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：235 / 238

页数：4

共 18 条

[1] FORMATION OF POLYCYCLIC AROMATIC-COMPOUNDS UPON ELECTRIC-DISCHARGES IN LIQUID TOLUENE [J].

BECK, MT ;

DINYA, Z ;

KEKI, S .

TETRAHEDRON, 1992, 48 (23) :4919-4928

[2] Growth process conditions of vertically aligned carbon nanotubes using plasma enhanced chemical vapor deposition [J].

Chhowalla, M ;

Teo, KBK ;

Ducati, C ;

Rupesinghe, NL ;

Amaratunga, GAJ ;

Ferrari, AC ;

Roy, D ;

Robertson, J ;

Milne, WI .

JOURNAL OF APPLIED PHYSICS, 2001, 90 (10) :5308-5317

[3] LARGE-SCALE SYNTHESIS OF CARBON NANOTUBES [J].

EBBESEN, TW ;

AJAYAN, PM .

NATURE, 1992, 358 (6383) :220-222

[4] THE PRODUCTION AND STRUCTURE OF PYROLYTIC CARBON NANOTUBES (PCNTS) [J].

ENDO, M ;

TAKEUCHI, K ;

IGARASHI, S ;

KOBORI, K ;

SHIRAISHI, M ;

KROTO, HW .

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1993, 54 (12) :1841-1848

[5]

Hsin YL, 2001, ADV MATER, V13, P830, DOI 10.1002/1521-4095(200106)13:11<830::AID-ADMA830>3.0.CO

[6]

2-4

[7] Nano-aggregates of single-walled graphitic carbon nano-horns [J].

Iijima, S ;

Yudasaka, M ;

Yamada, R ;

Bandow, S ;

Suenaga, K ;

Kokai, F ;

Takahashi, K .

CHEMICAL PHYSICS LETTERS, 1999, 309 (3-4) :165-170

[8] SINGLE-SHELL CARBON NANOTUBES OF 1-NM DIAMETER [J].

IIJIMA, S ;

ICHIHASHI, T .

NATURE, 1993, 363 (6430) :603-605

[9] HELICAL MICROTUBULES OF GRAPHITIC CARBON [J].

IIJIMA, S .

NATURE, 1991, 354 (6348) :56-58

[10] A simple method for the continuous production of carbon nanotubes [J].

Ishigami, M ;

Cumings, J ;

Zettl, A ;

Chen, S .

CHEMICAL PHYSICS LETTERS, 2000, 319 (5-6) :457-459

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