A color version of the Hinsberg test:: 1°-3° amine indicator

被引:16
作者
Kim, Jong Seung [1 ]
Lee, Soo Jin
Jung, Jong Hwa
Hwang, In-Chul
Singh, N. Jiten
Kim, Sung Kuk
Lee, Seoung Ho
Kim, Hyun Jung
Keum, Chang Soo
Lee, Jung Woo
Kim, Kwang S.
机构
[1] Dankook Univ, Dept Chem, Inst Nanosensor & Biotechnol, Seoul 140714, South Korea
[2] Gyeongsang Natl Univ, Dept Chem, Chinju 660701, South Korea
[3] Gyeongsang Natl Univ, Res Inst Nat Sci, Chinju 660701, South Korea
[4] Pohang Univ Sci & Technol, Dept Chem, Ctr Superfunct Mat, Pohang 790784, South Korea
关键词
calixarenes; Hinsberg test; receptors; sensors; supramolecular chemistry;
D O I
10.1002/chem.200600905
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The Hinsberg test to recognize the type of amine (1 degrees-3 degrees amines), which has been established for more than 100 years and well documented in textbooks, is not possible without conducting complicated organic reactions. We report for the first time unique chemosensors that are capable of showing selective color changes toward 1 degrees-3 degrees amines as a color version of the Hinsberg test. This simple and straightforward qualitative analysis, using the synthesized novel compounds herein, can be considered a new innovative tool for discriminating 1 degrees-3 degrees amines as an alternative to the historical Hinsberg test.
引用
收藏
页码:3082 / 3088
页数:7
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