A color version of the Hinsberg test:: 1°-3° amine indicator

被引：16

作者：

Kim, Jong Seung ^{[1
]}

Lee, Soo Jin

Jung, Jong Hwa

Hwang, In-Chul

Singh, N. Jiten

Kim, Sung Kuk

Lee, Seoung Ho

Kim, Hyun Jung

Keum, Chang Soo

Lee, Jung Woo

Kim, Kwang S.

机构：

[1] Dankook Univ, Dept Chem, Inst Nanosensor & Biotechnol, Seoul 140714, South Korea

[2] Gyeongsang Natl Univ, Dept Chem, Chinju 660701, South Korea

[3] Gyeongsang Natl Univ, Res Inst Nat Sci, Chinju 660701, South Korea

[4] Pohang Univ Sci & Technol, Dept Chem, Ctr Superfunct Mat, Pohang 790784, South Korea

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2007年 / 13卷 / 11期

关键词：

calixarenes; Hinsberg test; receptors; sensors; supramolecular chemistry;

D O I：

10.1002/chem.200600905

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Hinsberg test to recognize the type of amine (1 degrees-3 degrees amines), which has been established for more than 100 years and well documented in textbooks, is not possible without conducting complicated organic reactions. We report for the first time unique chemosensors that are capable of showing selective color changes toward 1 degrees-3 degrees amines as a color version of the Hinsberg test. This simple and straightforward qualitative analysis, using the synthesized novel compounds herein, can be considered a new innovative tool for discriminating 1 degrees-3 degrees amines as an alternative to the historical Hinsberg test.

引用

页码：3082 / 3088

页数：7

共 40 条

[21] ABIOTIC RECEPTORS [J].

HAYWARD, RC .

CHEMICAL SOCIETY REVIEWS, 1983, 12 (03) :285-308

[22]

HINSBERG O, 1890, CHEM BER, V23, P2963

[23] Novel cavity design using calix[n]arene skeletons: Toward molecular recognition and metal binding [J].

Ikeda, A ;

Shinkai, S .

CHEMICAL REVIEWS, 1997, 97 (05) :1713-1734

[24] AZOPHENOLIC ACERANDS - AMINE-SELECTIVE COLORATION AND CRYSTAL-STRUCTURE OF A PIPERIDINIUM SALTEX [J].

KANEDA, T ;

UMEDA, S ;

ISHIZAKI, Y ;

KUO, HS ;

MISUMI, S ;

KAI, Y ;

KANEHISA, N ;

KASAI, N .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (05) :1881-1883

[25] SYNTHESIS, COLORATION, AND CRYSTAL-STRUCTURE OF THE DIBASIC CHROMOACERAND PIPERAZINE 1-1 SALT COMPLEX [J].

KANEDA, T ;

ISHIZAKI, Y ;

MISUMI, S ;

KAI, Y ;

HIRAO, G ;

KASAI, N .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (09) :2970-2972

[26] 'Thiacalix[4]aniline' as a highly specific extractant for Au(III) and Pd(II) ions [J].

Katagiri, H ;

Iki, N ;

Matsunaga, Y ;

Kabuto, C ;

Miyano, S .

CHEMICAL COMMUNICATIONS, 2002, (18) :2080-2081

[27] Chromogenic azo-coupled calix[4]arenes [J].

Kim, JS ;

Shon, OJ ;

Lee, JK ;

Lee, SH ;

Kim, JY ;

Park, KM ;

Lee, SS .

JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (04) :1372-1375

[28] UV band splitting of chromogenic azo-coupled calix[4]crown upon cation complexation [J].

Kim, JY ;

Kim, G ;

Kim, CR ;

Lee, SH ;

Lee, JH ;

Kim, JS .

JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (05) :1933-1937

[29] Molecular clusters of π-systems:: Theoretical studies of structures, spectra, and origin of interaction energies [J].

Kim, KS ;

Tarakeshwar, P ;

Lee, JY .

CHEMICAL REVIEWS, 2000, 100 (11) :4145-4185

[30] Colorimetric chiral recognition by a molecular sensor [J].

Kubo, Y ;

Maeda, S ;

Tokita, S ;

Kubo, M .

NATURE, 1996, 382 (6591) :522-524

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