Perspectives in reductive lanthanide chemistry

被引:207
作者
Evans, WJ [1 ]
机构
[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA
基金
美国国家科学基金会;
关键词
lanthanide; reduction; steric; cyclopentadienyl; low valent; organometallic;
D O I
10.1016/S0010-8545(00)00267-8
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
For several decades the reductive chemistry of the lanthanide metals in soluble, fully characterized molecular species has focused primarily on just three elements: europium, ytterbium, and samarium. Recent developments suggest that the reductive chemistry of the lanthanides is likely to expand greatly beyond these three elements in the new millennium and will be a major area of advancement in lanthanide inorganic, organometallic, and coordination chemistry. This paper previews some possibilities in this held. (C) 2000 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:263 / 283
页数:21
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