A new ester substituted heteroscorpionate ligand

被引：8

作者：

Alidori, S

Pellei, M

Pettinari, C

Santini, C

Skelton, BW

White, AH

机构：

[1] Univ Camerino, Dipartimento Sci Chim, I-62032 Camerino, MC, Italy

[2] Univ Western Australia, Dept Chem, Crawley, WA 6009, Australia

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 09期

关键词：

copper(I) complexes; pyrazole; scorpionate ligands; crystal structure;

D O I：

10.1016/j.inoche.2004.07.017

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new dihydrobis(3 -carboxyethyl-5-methylpyrazolyl)borate ligand Bp(COOET,Me) is prepared as its potassium salt in kerosene solution, using ethyl 3-methylpyrazole-5-carboxylate and KBH4, through careful temperature control. Bp(COOET,Me) reacts with CuCl and PPh3 to yield the {Cu(Bp(COOET,Me))PPh3} complex. BPCOOET,Me and {Cu(BPCOOET, me)PPh3) have been fully characterized by elemental analyses and FT-IR in the solid state and by NMR (H-1, C-13 and (31)p) spectroscopy and electrospray ionization mass spectrometry in solution. A single crystal structural characterization is reported for {Cu(Bp(COOET,Me))PPh3]. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：1075 / 1077

页数：3

共 23 条

[1] Zinc complexes of hydrogen bond accepting ester substituted trispyrazolylborates [J].