A germanium alkoxide supported by a C3-symmetric ligand for the stereoselective synthesis of highly heterotactic polylactide under solvent-free conditions

被引：157

作者：

Chmura, Amanda J.

Chuck, Christopher J.

Davidson, Matthew G.

Jones, Matthew D.

Lunn, Matthew D.

Bull, Steven D.

Mahon, Mary F.

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

[2] Johnson Matthey Catalysts, Billingham TS2 1LB, Cleveland, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 13期

关键词：

germanium alkoxides; homogeneous catalysis; ring-opening polymerization; tripodal ligands; X-ray diffraction;

D O I：

10.1002/anie.200603944

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Ge whiz: Highly stereoselective bulk ring-opening polymerization of rac-lactide to afford a heterotactic polymer was achieved for the first time through the use of a single-site germanium alkoxide initiator. The C3 symmetry of the ligand may play an important role in controlling stereoselective chain propagation from the racemic monomer. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：2280 / 2283

页数：4

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