Synthesis and photophysical properties of a new cationic water-soluble Zn phthalocyanine

被引：48

作者：

Fernandez, DA

Awruch, J

Dicelio, LE

机构：

[1] Univ Buenos Aires, Fac Ciencias Exactas & Nat, Dept Quim Inorgan Analit & Quim Fis, INQUIMAE, RA-1428 Buenos Aires, DF, Argentina

[2] Univ Buenos Aires, Fac Farm & Bioquim, Dept Quim Organ, RA-1113 Buenos Aires, DF, Argentina

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY B-BIOLOGY | 1997年 / 41卷 / 03期

关键词：

cationic phthalocyanine; phthalocyanine; zinc;

D O I：

10.1016/S1011-1344(97)00106-1

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The synthesis of tetrakis(1,1-dimethyl-2-trimethylammonium)ethylphthalocyaninato Zn(II) tetraiodide 2-a new cationic phthalocyanine - is reported as well as its photophysical properties in water, relevant for the use of this dye as photodynamic sensitizer. The hydrophobicity of the macrocycle leads to strong aggregation which lowers the fluorescence and singlet oxygen quantum yields of aqueous solutions of 2. Photophysical parameters agree with those of other Zn phthalocyanines when correction is performed for the fraction of light absorbed by the monomer. (C) 1997 Elsevier Science S.A.

引用

页码：227 / 232

页数：6

共 37 条

[11] FAST-ATOM-BOMBARDMENT MASS-SPECTRA OF SOME TETRA-NORMAL-BUTYLAMMONIUM SALTS [J].

FURTON, KG ;

POOLE, CF .

ORGANIC MASS SPECTROMETRY, 1987, 22 (06) :377-378

[12]

HAISCH P, 1995, SYNTHESIS-STUTTGART, P1251

[13] ATTEMPTED PHOTOPRODUCTION OF HYDROGEN USING SULFOPHTHALOCYANINES AS CHROMOPHORES FOR 3-COMPONENT SYSTEMS [J].

HARRIMAN, A ;

RICHOUX, MC .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1980, 76 :1618-1626

[14] THE DISCOVERY OF THE CHEMICAL EVOLUTION OF SINGLET OXYGEN - SOME CURRENT CHEMICAL, PHOTOCHEMICAL, AND BIOLOGICAL APPLICATIONS [J].

KHAN, AU .

INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY, 1991, 39 (03) :251-267

[15] DETERMINATION OF EQUILIBRIUM-CONSTANTS BY CHEMOMETRIC ANALYSIS OF SPECTROSCOPIC DATA [J].

KUBISTA, M ;

SJOBACK, R ;

ALBINSSON, B .

ANALYTICAL CHEMISTRY, 1993, 65 (08) :994-998

[16]

LAGORIO MG, 1993, J PHOTOCH PHOTOBIO A, V72, P153

[17]

MANG TS, 1993, CANCER, V71, P269, DOI 10.1002/1097-0142(19930101)71:1<269::AID-CNCR2820710141>3.0.CO

[18]

2-R

[19]

MARRUGAT SNI, 1988, THESIS M PLANCK I ST

[20] Meso-substituted cationic porphyrins as efficient photosensitizers of gram-positive and gram-negative bacteria [J].

Merchat, M ;

Bertolini, G ;

Giacomini, P ;

Villanueva, A ;

Jori, G .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY B-BIOLOGY, 1996, 32 (03) :153-157

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