β-[H2N(CH2)2NH2]0.5[ZnHPO3], a second modification of ethylenediamine zinc hydrogen phosphite

被引：8

作者：

Gordon, LE ^{[1
]}

Harrison, WTA ^{[1
]}

机构：

[1] Univ Aberdeen, Dept Chem, Aberdeen AB24 3UE, Scotland

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2004年 / 60卷

关键词：

D O I：

10.1107/S0108270104027039

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, poly[dizinc( II)-mu-ethylenediamine-di-mu( hydrogen phosphito)], beta-[H2N(CH2)(2)NH2](0.5)[ZnHPO3] or [Zn-2(HPO3)(2)(C2H8N2)](n), is a hybrid organic/inorganic solid built up from ethylenediamine molecules ( which lie about inversion centres), Zn2+ cations (coordinated by three O atoms and one N atom) and HPO32- hydrogen phosphite groups. The organic species bond to the Zn atom as unprotonated ligands, acting as bridges between infinite ZnHPO3 layers that propagate as very buckled ( 001) sheets. The zincophosphite sheets contain polyhedral four- and eight-membered rings in a 4.8(2) topology. beta-[H2N(CH2)(2)NH2] (0.5) . ZnHPO3 complements the previously described alpha modification of the same stoichiometry [ Rodgers & Harrison (2000). Chem. Commun. pp. 2385 - 2386].

引用

页码：M637 / M639

页数：3

共 17 条

[1]

Alberti G, 1999, ANGEW CHEM INT EDIT, V38, P3351, DOI 10.1002/(SICI)1521-3773(19991115)38:22<3351::AID-ANIE3351>3.0.CO

[2]

2-V

[3]

*BRUK AXS INC, 1999, SMART VRS 5 624 SAIN

[4]

Cheetham AK, 1999, ANGEW CHEM INT EDIT, V38, P3268, DOI 10.1002/(SICI)1521-3773(19991115)38:22<3268::AID-ANIE3268>3.0.CO

[5]

2-U

[6]

Choudhury A, 2002, ANGEW CHEM INT EDIT, V41, P158, DOI 10.1002/1521-3773(20020104)41:1<158::AID-ANIE158>3.0.CO

[7]

2-#

[8] ORTEP-3 for Windows - a version of ORTEP-III with a Graphical User Interface (GUI) [J].

Journal of Applied Crystallography, 1997, 30 (pt 5)

[9] Synthesis and characterization of an organically-templated zincophosphite:: [C6H16N2]•Zn3(HPO3)4 [J].

Fu, WS ;

Shi, Z ;

Li, GN ;

Zhang, D ;

Dong, WJ ;

Chen, XB ;

Feng, SH .

SOLID STATE SCIENCES, 2004, 6 (02) :225-228

[10] Two zincophosphite frameworks templated by 1,4-diaminobenzene:: syntheses and structures of C6N2H10•Zn(HPO3)2 and (C6N2H8)0.5•ZnHPO3 [J].

Kirkpatrick, A ;

Harrison, WTA .

SOLID STATE SCIENCES, 2004, 6 (06) :593-598

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