Reactions of 3-phenyloxetane and 7-oxabicyclo[2.2.1]heptane with dinitrogen pentoxide in dichloromethane

被引：3

作者：

Dormer, JC ^{[1
]}

Hylands, KA ^{[1
]}

Moodie, RB ^{[1
]}

机构：

[1] Univ Exeter, Dept Chem, Exeter EX4 4QD, Devon, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1998年 / 02期

关键词：

D O I：

10.1039/a707260k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

3-Phenyloxetane reacts initially almost entirely by ortho and para aromatic nitration, This is followed by oxetane ring-opening to give the corresponding 2-arylpropane-1,3-diol dinitrates. The oxetane ring-opening reactions, and the reaction of 7-oxabicyclo[2.2.1]heptane to give exclusively trans-cyclohexane-1,4-diol dinitrate, are approximately second order in dinitrogen pentoxide and have highly negative entropies of activation.

引用

页码：243 / 246

页数：4

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