Reaction of elemental sulfur with a copper(I) complex forming a trans-μ-1,2 end-on disulfide complex:: New directions in copper-sulfur chemistry

被引：71

作者：

Helton, ME

Chen, P

Paul, PP

Tyeklár, Z

Sommer, RD

Zakharov, LN

Rheingold, AL

Solomon, EI

Karlin, KD ^{[1
]}

机构：

[1] Stanford Univ, Dept Chem, Stanford, CA 94305 USA

[2] Johns Hopkins Univ, Dept Chem, Baltimore, MD 21218 USA

[3] Univ Delaware, Dept Chem, Newark, DE 19716 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 05期

关键词：

D O I：

10.1021/ja027574j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Elemental sulfur (S8) was found to react with [(TMPA)CuI(CH3CN)]+ to form the trans-μ-1,2 end-on disulfide complex [(TMPA)Cu-S-S-Cu(TMPA)]2+. The X-ray structure of this centrosymmetric disulfide complex shows a Cu(1)-S(1) bond length of 2.280(2) Å and a S(1)-S(1A) bond length of 2.044(4) Å. Copyright © 2003 American Chemical Society.

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页码：1160 / 1161

页数：2

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