Highly water soluble C60 derivatives:: A new synthesis

被引：29

作者：

Arrais, A ^{[1
]}

Diana, E ^{[1
]}

机构：

[1] Univ Turin, Dipartimento Chim IFM, I-10125 Turin, Italy

来源：

FULLERENES NANOTUBES AND CARBON NANOSTRUCTURES | 2003年 / 11卷 / 01期

关键词：

fullerene; water solubility; solid state spectroscopies;

D O I：

10.1081/FST-120018667

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Unprecedented protocol, consisting in reduction of Buckminsterfullerene with Na/K alloy and successive stirring in presence Of 62, affords polyhydroxylated fullerenols which are highly water soluble, from strongly basic to medium acidic conditions. The products have been characterized by means of cross polarization magic angle spinning (CPMAS) NMR, H-1-NMR, electron, FT-IR, Raman and mass spectroscopies. Possible paths of reaction and the role of molecular oxygen in fullerene cage-oxidation are discussed.

引用

页码：35 / 46

页数：12

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