Hybrid solar cells based on porous Si and copper phthalocyanine derivatives

被引:56
作者
Levitsky, IA [1 ]
Euler, WB
Tokranova, N
Xu, B
Castracane, J
机构
[1] Emitech Inc, Fall River, MA 02720 USA
[2] Univ Rhode Isl, Dept Chem, Kingston, RI 02881 USA
[3] SUNY Albany, Coll Nanoscale Sci & Engn, Albany, NY 12203 USA
关键词
D O I
10.1063/1.1839280
中图分类号
O59 [应用物理学];
学科分类号
摘要
We demonstrate a solar cell based on n-type nanoporous Si (PSi) filled with copper phthalocyanine (CuPC) and its derivatives (including a discotic liquid crystal form). The CuPC device shows conversion efficiency up to 2% under white light illumination (20-30 mW/cm(2)), distinct from cells filled with CuPC derivatives with alkyl chains attached to the core. It is concluded that a critical issue for efficient photocarrier generation is the distance between the CuPC core and the PSi surface. Both organic and inorganic components contribute to photoinduced charge transfer and transport processes. The influence of the PSi structure and pore filling on the solar cell performance is discussed. (C) 2004 American Institute of Physics.
引用
收藏
页码:6245 / 6247
页数:3
相关论文
共 23 条
[1]   Growth of organic semiconductors for hybrid solar cell application [J].
Ackermann, J ;
Videlot, C ;
El Kassmi, A .
THIN SOLID FILMS, 2002, 403 :157-161
[2]  
Ago H, 1999, ADV MATER, V11, P1281, DOI 10.1002/(SICI)1521-4095(199910)11:15<1281::AID-ADMA1281>3.0.CO
[3]  
2-6
[4]  
[Anonymous], 1981, PHYS SEMICONDUCTOR D
[5]   Hybrid organic-on-inorganic photovoltaic devices [J].
Garnier, F .
JOURNAL OF OPTICS A-PURE AND APPLIED OPTICS, 2002, 4 (06) :S247-S251
[6]   Dye-sensitized solar cells [J].
Grätzel, M .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS, 2003, 4 (02) :145-153
[7]   Charge separation and transport in conjugated-polymer/semiconductor-nanocrystal composites studied by photoluminescence quenching and photoconductivity [J].
Greenham, NC ;
Peng, XG ;
Alivisatos, AP .
PHYSICAL REVIEW B, 1996, 54 (24) :17628-17637
[8]   Excitonic solar cells [J].
Gregg, BA .
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (20) :4688-4698
[9]   Hybrid nanorod-polymer solar cells [J].
Huynh, WU ;
Dittmer, JJ ;
Alivisatos, AP .
SCIENCE, 2002, 295 (5564) :2425-2427
[10]   Interface formation between thin Cu-phthalocyanine films and crystalline and oxidized silicon surfaces [J].
Komolov, AS ;
Moller, PJ .
SYNTHETIC METALS, 2002, 128 (02) :205-210