Time resolved infrared spectroscopy as a technique to study reactive organometallic intermediates

被引：24

作者：

McFarlane, K ^{[1
]}

Lee, B ^{[1
]}

Bridgewater, J ^{[1
]}

Ford, PC ^{[1
]}

机构：

[1] Univ Calif Santa Barbara, Dept Chem, Santa Barbara, CA 93106 USA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1998年 / 554卷 / 01期

基金：

美国国家科学基金会;

关键词：

time resolved infrared spectroscopy; manganese; cobalt; iron;

D O I：

10.1016/S0022-328X(97)00600-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The application of time resolved infrared spectroscopy to problems in organometallic chemistry is discussed and an overview of different techniques to record TRIR spectra ranging from mu s to fs time scales is presented. More detailed examples of TRIR applications in organometallic chemistry from the authors' laboratory are summarized. These are concerned with elucidating the natures and reaction dynamics of intermediates in the migratory insertion of CO into the metal-alkyl bonds of manganese and cobalt carbonyls and of cyclopentadienyl iron complexes. (C) 1998 Elsevier Science S.A.

引用

页码：49 / 61

页数：13

共 51 条

[1]

Alfano R. R., 1989, SUPERCONTINUUM LASER

[2]

ALLEVI M, 1996, J CHEM SOC DA, P3727

[3]

ANFINRUD P, 1988, SPRINGER SERIES CHEM, V48, P442

[4] EVOLUTION OF THE TRANSIENT VIBRATIONAL-SPECTRUM FOLLOWING SHORT-PULSE EXCITATION [J].

ANFINRUD, PA ;

HAN, C ;

LIAN, T ;

HOCHSTRASSER, RM .

JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (03) :1180-1184

[5] FEMTOSECOND INFRARED-SPECTROSCOPY - ULTRAFAST PHOTOCHEMISTRY OF IRON CARBONYLS IN SOLUTION [J].

ANFINRUD, PA ;

HAN, CH ;

LIAN, TQ ;

HOCHSTRASSER, RM .

JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (02) :574-578

[6] REACTIVE INTERMEDIATES IN THE PHOTOLYTIC DECARBONYLATION OF THE ACYL COMPLEX (ETA-5-C5H5)FE(CO)2(COCH3) AS STUDIED BY TIME-RESOLVED INFRARED SPECTRAL TECHNIQUES [J].

BELT, ST ;

RYBA, DW ;

FORD, PC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (25) :9524-9528

[7] PHOTOLYSIS OF GROUP-VI METAL-CARBONYLS, (ETA-6-C6H6)CR(CO)3, (ETA-5-C5H5)MN(CO)3, (ETA-5-CH3C5H4)MN(CO)3 AND (ETA-5-C5H5)RE(CO)3 IN NUJOL AT 77-K [J].

BITTERWOLF, TE ;

LOTT, KA ;

REST, AJ ;

MASCETTI, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 419 (1-2) :113-126

[8] DINUCLEAR, 18-ELECTRON SPECIES HAVING A TRIPLET GROUND-STATE - ISOLATION, CHARACTERIZATION, AND CRYSTAL-STRUCTURE OF PHOTOGENERATED (ETA-2-C5ME5)2FE2(MU-CO)3 [J].

BLAHA, JP ;

BURSTEN, BE ;

DEWAN, JC ;

FRANKEL, RB ;

RANDOLPH, CL ;

WILSON, BA ;

WRIGHTON, MS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (15) :4561-4562

[9] INTERMEDIATES RELEVANT TO THE CARBONYLATION OF MANGANESE ALKYL COMPLEXES INTERROGATED BY TIME-RESOLVED INFRARED AND OPTICAL SPECTROSCOPY [J].

BOESE, WT ;

FORD, PC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (32) :8381-8391

[10] TIME-RESOLVED INFRARED SPECTRAL STUDIES OF INTERMEDIATES FORMED IN THE LASER FLASH-PHOTOLYSIS OF MN(CO)(5)CH3 [J].

BOESE, WT ;

FORD, PC .

ORGANOMETALLICS, 1994, 13 (09) :3525-3531

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