Time resolved infrared spectroscopy as a technique to study reactive organometallic intermediates

被引：24

作者：

McFarlane, K ^{[1
]}

Lee, B ^{[1
]}

Bridgewater, J ^{[1
]}

Ford, PC ^{[1
]}

机构：

[1] Univ Calif Santa Barbara, Dept Chem, Santa Barbara, CA 93106 USA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1998年 / 554卷 / 01期

基金：

美国国家科学基金会;

关键词：

time resolved infrared spectroscopy; manganese; cobalt; iron;

D O I：

10.1016/S0022-328X(97)00600-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The application of time resolved infrared spectroscopy to problems in organometallic chemistry is discussed and an overview of different techniques to record TRIR spectra ranging from mu s to fs time scales is presented. More detailed examples of TRIR applications in organometallic chemistry from the authors' laboratory are summarized. These are concerned with elucidating the natures and reaction dynamics of intermediates in the migratory insertion of CO into the metal-alkyl bonds of manganese and cobalt carbonyls and of cyclopentadienyl iron complexes. (C) 1998 Elsevier Science S.A.

引用

页码：49 / 61

页数：13

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