A route to the synthesis of trivalent transition-metal porous carboxylates with trimeric secondary building units

被引：475

作者：

Serre, C ^{[1
]}

Millange, F ^{[1
]}

Surblé, S ^{[1
]}

Férey, G ^{[1
]}

机构：

[1] Univ Versailles St Quentin Yvelines, CNRS, UMR 8637, Inst Lavoisier, F-78035 Versailles, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 46期

关键词：

carboxylates; host-guest systems; iron; nanoporous materials; organic-inorganic hybrid composites;

D O I：

10.1002/anie.200454250

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Prefabricated construction techniques: A solvothermal route involving iron(III) trimeric secondary building units has been developed. Two new open-framework iron (III) dicarboxylates have been characterized from X-ray powder diffraction studies. Their 3D structures are built up from trimers of iron polyhedra related through dicarboxylates, thus creating cationic frameworks with 1D pore systems filled with solvent molecules and anions (see example). (Figure presented).

引用

页码：6286 / 6289

页数：4

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