The spreading of silicone oil droplets on a surface with parallel V-shaped grooves

被引:28
作者
Gerdes, S
Cazabat, AM
Strom, G
机构
[1] Inst Surface Chem, S-11486 Stockholm, Sweden
[2] Coll France, F-75231 Paris 05, France
[3] Stora Corp Res AB, S-79180 Falun, Sweden
关键词
D O I
10.1021/la970139w
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this paper we report on dynamic wetting studies on model rough surfaces. A series of well-defined model surfaces has been manufactured, and the dynamic wetting of silicone oil droplets on these surfaces has been studied. The surface structures are etched, parallel, V-shaped grooves with varying width and spacing. Spreading has been studied in two different time regimes with two different techniques. At "short times", the Liquid does not penetrate significantly inside the grooves ahead of the edge of the main drop. At "long times", the penetration of liquid inside the grooves is significant and the grooves are practically filled up at the edge of the main drop, which we consider as the "contact line". In both regimes, contact Line velocity, v, and dynamic contact angle, theta, are measured in the flat parts between grooves. The spreading parallel to the grooves is described by Tanner-like laws in both cases but with different characteristics: At short times, the spreading velocity increases with the area covered by grooves. At long times no effect ofthe grooves is observed until the distance between the grooves is smaller than approximately 30 mu m. In this case, it appears that the effect is correlated with the disturbance of the contact line due to the interaction of the groove "defects".
引用
收藏
页码:7258 / 7264
页数:7
相关论文
共 48 条
[31]   EQUILIBRIUM AND SPREADING OF LIQUIDS ON SOLID-SURFACES [J].
MARMUR, A .
ADVANCES IN COLLOID AND INTERFACE SCIENCE, 1983, 19 (1-2) :75-102
[32]   DYNAMICS OF CONTACT LINE DEPINNING FROM A SINGLE DEFECT [J].
MARSH, JA ;
CAZABAT, AM .
PHYSICAL REVIEW LETTERS, 1993, 71 (15) :2433-2436
[33]   ON THE NATURE OF THE DYNAMIC CONTACT-ANGLE - AN EXPERIMENTAL-STUDY [J].
NGAN, CG ;
DUSSAN, EB .
JOURNAL OF FLUID MECHANICS, 1982, 118 (MAY) :27-40
[34]   QUASI-STATIC SHAPE OF THE STEADY MOVING MENISCUS - COMPARISON OF THE APPARENT AND EXTRAPOLATED DYNAMIC CONTACT ANGLES [J].
PETROV, JG ;
SEDEV, RV .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1993, 74 (2-3) :233-241
[35]   STEADY MOTION OF THE 3 PHASE CONTACT LINE IN MODEL LANGMUIR-BLODGETT SYSTEMS [J].
PETROV, JG ;
RADOEV, BP .
COLLOID AND POLYMER SCIENCE, 1981, 259 (07) :753-760
[36]   A COMBINED MOLECULAR-HYDRODYNAMIC APPROACH TO WETTING KINETICS [J].
PETROV, PG ;
PETROV, JG .
LANGMUIR, 1992, 8 (07) :1762-1767
[37]   THE MOVING CONTACT LINE OF A DROPLET ON A SMOOTH SOLID [J].
RUCKENSTEIN, E .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1995, 170 (01) :284-286
[38]   The flow of liquids in surface grooves [J].
Rye, RR ;
Mann, JA ;
Yost, FG .
LANGMUIR, 1996, 12 (02) :555-565
[39]   MATHEMATICAL-MODELING OF WETTING HYDRODYNAMICS [J].
SHIKHMURZAEV, YD .
FLUID DYNAMICS RESEARCH, 1994, 13 (01) :45-64
[40]   SPREADING OF LIQUID-DROPS OVER DRY SURFACES [J].
STAROV, VM ;
KALININ, VV ;
CHEN, JD .
ADVANCES IN COLLOID AND INTERFACE SCIENCE, 1994, 50 :187-221