Synthesis of chiral molecules containing pyridine and 1,3-pyrimidine units:: Potential building blocks for helicating and caging ligands

被引：11

作者：

Pezet, F ^{[1
]}

Routaboul, L ^{[1
]}

Daran, JC ^{[1
]}

Sasaki, I ^{[1
]}

Aït-Haddou, H ^{[1
]}

Balavoine, GGA ^{[1
]}

机构：

[1] CNRS, Chim Coordinat Lab, UPR 8241, F-31077 Toulouse 4, France

来源：

TETRAHEDRON | 2000年 / 56卷 / 43期

关键词：

asymmetric reactions; enamines; amidines; pyrimidines; pyridines; molecular design;

D O I：

10.1016/S0040-4020(00)00795-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A simple and efficient method for the synthesis of new chiral polyaza heterocylic structures containing pyridines and 1,3-pyrimidine units has been developed. It is based on the reaction of the appropriate enaminones with optically pure carboxamidine derived from the commercially available (R)-(-)-myrtenal. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：8489 / 8493

页数：5

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