Langmuir monolayers of polyphenylene carboxylic acids

被引:10
作者
Czapkiewicz, J [1 ]
Dynarowicz-Latka, P [1 ]
Janicka, G [1 ]
Milart, P [1 ]
机构
[1] Jagiellonian Univ, Fac Chem, PL-30060 Krakow, Poland
关键词
Langmuir monolayers; polyphenylene; carboxylic acids;
D O I
10.1016/S0927-7757(97)00223-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A series of polyphenyl carboxylic acids with 3-6 uncondensed benzene rings and some of their analogues with a nitro and/or cyano group were synthesized and investigated at the air-water interface. They all can be treated as substituted m-terphenyls. It is determined that a system with at least four phenyl groups with the carboxyl group at a peripheral position are a prerequisite for the ability of monolayer formation. Their isotherms exhibit a large plateau attributed to the formation of bilayers. (C) 1998 Elsevier Science B.V.
引用
收藏
页码:149 / 156
页数:8
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