Silver selenide nanowires by electrodeposition

被引：17

作者：

Chen, RZ ^{[1
]}

Xu, DS ^{[1
]}

Guo, GL ^{[1
]}

Gui, LL ^{[1
]}

机构：

[1] Peking Univ, State Key Lab Struct Chem Unstable & Stable Speci, Inst Phys Chem, Beijing 100871, Peoples R China

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 2003年 / 150卷 / 03期

关键词：

D O I：

10.1149/1.1540065

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Silver selenide nanowires were synthesized by potentiostatic electrodeposition into porous anodic alumina membranes from an aqueous acid electrolyte containing silver ion complexed with SCN- and selenium dioxide at room temperature. Electron microscopy results showed that the lengths, diameters, and growth directions of the nanowires are quite uniform. X-ray energy dispersion analysis indicated that the nanowires are composed of Ag and Se with an atomic ratio of Ag/Se = 2.08, which is close to stoichiometric Ag2Se. X-ray diffraction patterns showed that the as-deposited nanowires are polycrystalline orthorhombic beta-Ag2Se, and the annealed nanowires are highly [002] oriented. Furthermore, the selected area electron diffraction pattern and the high-resolution transmission electron microscopy image demonstrated that after annealing the nanowires have a uniform crystalline structure of orthorhombic beta-Ag2Se, which are (002) oriented along the direction vertical to the wire axes. (C) 2003 The Electrochemical Society.

引用

页码：G183 / G186

页数：4

共 30 条

[21]

SKYLLAS-KAZACOS M, 1980, J ELECTROCHEM SOC, V127, P869, DOI 10.1149/1.2129772

[22] HYSTERESIS OF THE PHASE-TRANSFORMATION DETECTED BY GALVANOMAGNETIC MEASUREMENTS OF AG2SE LAYERS [J].