A novel interpenetrating 2-D brush-like structure:: hydrothermal synthesis and crystal,structure of [Cu(phen)V4O10]∞ (phen=1,10-phenanthroline)

被引:9
作者
Cui, XB
Lin, ZE
Yang, GY [1 ]
机构
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, Coordinat & Hydrothermal Chem Grp, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
vanadium oxide; inorganic-organic hybrid material; hydrothermal synthesis; crystal structure;
D O I
10.1016/S1293-2558(03)00006-2
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A novel vanadium oxides [Cu(phen)V4O10](infinity) (1), has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction, elemental analysis, IR, EPR spectroscopy and thermal analysis. The compound crystallizes in monoclinic structure of P2(1)/m with a = 7.4169(10) Angstrom, b = 10.0460(13) Angstrom, c = 11.0845(15) Angstrom, beta = 102.520(2)degrees, V = 806.27(19) Angstrom(3) and Z = 2. (C) 2003 Editions scientifiques et medicales Elsevier SAS. All rights reserved.
引用
收藏
页码:311 / 315
页数:5
相关论文
共 13 条
[1]   BOND-VALENCE PARAMETERS FOR SOLIDS [J].
BRESE, NE ;
OKEEFFE, M .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1991, 47 :192-197
[2]   MECHANISTIC ASPECTS OF MALEIC-ANHYDRIDE SYNTHESIS FROM C4-HYDROCARBONS OVER PHOSPHORUS VANADIUM-OXIDE [J].
CENTI, G ;
TRIFIRO, F ;
EBNER, JR ;
FRANCHETTI, VM .
CHEMICAL REVIEWS, 1988, 88 (01) :55-80
[3]   One-dimensional vanadium oxide chains containing covalently bound copper coordination complexes: Hydrothermal synthesis and characterization of Cu(H2N(CH2)(2)NH2)[V2O6], Cu(C10H8N2)[V2O6], and Cu(C10H8N2)(2)[V2O6] [J].
DeBord, JRD ;
Zhang, YP ;
Haushalter, RC ;
Zubieta, J ;
OConnor, CJ .
JOURNAL OF SOLID STATE CHEMISTRY, 1996, 122 (02) :251-258
[4]   Main-group element, organic, and organometallic derivatives of polyoxometalates [J].
Gouzerh, P ;
Proust, A .
CHEMICAL REVIEWS, 1998, 98 (01) :77-111
[5]   Inorganic-organic hybrids derived from oxovanadium sulfate motifs:: synthesis and characterization of [VIVO( μ3-SO4)(2,2′-bpy)]∞ [J].
Khan, MI ;
Cevik, S ;
Doedens, RJ .
CHEMICAL COMMUNICATIONS, 2001, (19) :1930-1931
[6]   Dehydrogenative coupling of phenanthroline under hydrothermal conditions:: crystal structure of a novel layered vanadate complex constructed of 4,8,10-net sheets:: [(2,2′-biphen)Co]V3O8.5 [J].
Liu, CM ;
Gao, S ;
Kou, HZ .
CHEMICAL COMMUNICATIONS, 2001, (17) :1670-1671
[7]   INTERCALATED VANADYL VANADATE (V(IV)O)[V(V)O4]CENTER-DOT-0.5[C3N2H12] - HYDROTHERMAL SYNTHESIS, CRYSTAL-STRUCTURE, AND STRUCTURAL CORRELATIONS WITH V2O5 AND OTHER VANADYL COMPOUNDS [J].
RIOU, D ;
FEREY, G .
JOURNAL OF SOLID STATE CHEMISTRY, 1995, 120 (01) :137-145
[8]  
RIOU D, 1995, INORG CHEM, V34, P2560
[9]   Inorganic/organic hybrid materials: Layered vanadium oxides with interlayer metal coordination complexes [J].
Shi, Z ;
Zhang, LR ;
Zhu, GS ;
Yang, GY ;
Hua, J ;
Ding, H ;
Feng, SH .
CHEMISTRY OF MATERIALS, 1999, 11 (12) :3565-3570
[10]   Hydrothermal synthesis and crystal structures of two bimetallic chain-like and cluster complexes [{Co(phen)2}2V6O17]n and [{Cu(phen)2}4V10O29]•6H2O [J].
Zhang, XM ;
Tong, ML ;
Chen, XM .
CHEMICAL COMMUNICATIONS, 2000, (18) :1817-1818