Synthesis of a [2]catenane around a Ru(diimine)32+ scaffold by ring-closing metathesis of olefins

被引：58

作者：

Arico, F ^{[1
]}

Mobian, P ^{[1
]}

Kern, JM ^{[1
]}

Sauvage, JP ^{[1
]}

机构：

[1] Univ Strasbourg 1, UMR 7513 CNRS, Lab Chim Organominerale, Fac Chim, F-67070 Strasbourg, France

来源：

ORGANIC LETTERS | 2003年 / 5卷 / 11期

关键词：

D O I：

10.1021/ol0300367

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of a ruthenium[2]catenane is described. One ring includes two 1,10-phenanthroline moieties, the other a bipyridinic unit. The interlocking ring system was formed by using a double ring closing metathesis reaction. Under irradiation, a rapid and selective decoordination of the bipyridinic fragment was observed, leading to a new catenane in which the metal is only coordinated to the bis-phenanthroline moiety.

引用

页码：1887 / 1890

页数：4

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