Micro-patterning of vapor-phase polymerized poly(3,4-ethylenedioxythiophene) (PEDOT) using ink-jet printing/soft lithography

被引:53
作者
Choi, Jong Seob [1 ]
Cho, Kuk Young [1 ]
Yim, Jin-Heong [1 ]
机构
[1] Kongju Natl Univ, Div Adv Mat Engn, Kong Ju 314701, Chungnam, South Korea
关键词
Imidazole derivatives; Ink-jet printing; Poly(3,4-ethylenedioxithiophene); Soft lithography; Vapor-phase polymerization; CONDUCTING POLYMERS; SOFT LITHOGRAPHY; POLYPYRROLE; MICROSTRUCTURES; TRANSPARENT; FABRICATION;
D O I
10.1016/j.eurpolymj.2009.11.010
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Highly conductive and transparent poly(3,4-ethylenedioxythiophene) (PEDOT) thin films can be prepared effectively via vapor-phase polymerization (VPP) with the addition of imidazole (1m) based derivatives. The addition of 1m that has one and/or two alkyl substituents significantly improved the electrical conductivity of PEDOT thin films. In an effort to develop a facile PEDOT micro-patterning method, we investigated ink-jet printing and soft lithography. The procedure of oxidant patterning with a weak base followed by VPP of a 3,4-ethylenedioxythiophene (EDOT) monomer provides an effective and simple method for micro-patterning of an intrinsic conductive polymer (ICP). (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码:389 / 396
页数:8
相关论文
共 25 条
[1]  
Beh WS, 1999, ADV MATER, V11, P1038, DOI 10.1002/(SICI)1521-4095(199908)11:12<1038::AID-ADMA1038>3.0.CO
[2]  
2-L
[3]   ELECTROPLATING OF CONDUCTIVE POLYMERS FOR THE METALLIZATION OF INSULATORS [J].
DELEEUW, DM ;
KRAAKMAN, PA ;
BONGAERTS, PEG ;
MUTSAERS, CMJ ;
KLAASSEN, DBM .
SYNTHETIC METALS, 1994, 66 (03) :263-273
[4]   Conductive elastomeric foams prepared by in situ vapor phase polymerization of pyrrole and copolymerization of pyrrole and N-methylpyrrole [J].
Fu, YP ;
Weiss, RA ;
Gan, PP ;
Bessette, MD .
POLYMER ENGINEERING AND SCIENCE, 1998, 38 (05) :857-862
[5]  
Granlund T, 2000, ADV MATER, V12, P269, DOI 10.1002/(SICI)1521-4095(200002)12:4<269::AID-ADMA269>3.0.CO
[6]  
2-5
[7]   Towards a transparent, highly conductive poly(3,4-ethylenedioxythiophene) [J].
Ha, YH ;
Nikolov, N ;
Pollack, SK ;
Mastrangelo, J ;
Martin, BD ;
Shashidhar, R .
ADVANCED FUNCTIONAL MATERIALS, 2004, 14 (06) :615-622
[8]   Ultraviolet embossed alignment layer for flexible liquid crystal display [J].
Hah, Hyundae ;
Sung, Shi-Joon ;
Park, Jung-Ki .
APPLIED PHYSICS LETTERS, 2007, 90 (06)
[9]   Micropatterning of a stretchable conductive polymer using inkjet printing and agarose stamping [J].
Hansen, Thomas Steen ;
Hassager, Ole ;
Larsen, Niels B. ;
Clark, Noel B. .
SYNTHETIC METALS, 2007, 157 (22-23) :961-967
[10]   Direct fast Patterning of conductive polymers using agarose stamping [J].
Hansen, Thomas Steen ;
West, Keld ;
Hassager, Ole ;
Larsen, Niels B. .
ADVANCED MATERIALS, 2007, 19 (20) :3261-+