Crystal structure and metamagnetic property of a 2-D layered complex, [FeII(N3)2(pyz)]n (pyz = pyrazine)

被引：89

作者：

Hao, X ^{[1
]}

Wei, YG ^{[1
]}

Zhang, SW ^{[1
]}

机构：

[1] Peking Univ, Dept Chem, Beijing 100871, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 22期

关键词：

D O I：

10.1039/b005137n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In crystals of [Fe-II(N-3)(2)(pyz)](n) (pyz = pyrazine), two adjacent Fe2+ ions are bridged via two mu -1,1-N-3(-) ligands along the c axis to afford ferromagnetically coupled linear chains, which are bridged via mu -pyrazine ligands along the b axis to afford 2-D antiferromagnetically coupled layers; these competitive magnetic couplings lead to the occurrence of metamagnetic behavior.

引用

页码：2271 / 2272

页数：2

共 14 条

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