Ion transport in nanofluidic channels

被引:472
作者
Daiguji, Hirofumi [1 ,2 ]
机构
[1] Univ Tokyo, Grad Sch Frontier Sci, Inst Environm Studies, Kashiwa, Chiba 2778563, Japan
[2] Univ Tokyo, Dept Mech Engn, Hongo 1138656, Japan
基金
日本学术振兴会;
关键词
MESOPOROUS SILICA FILMS; INORGANIC NANOTUBES; CARBON NANOTUBE; DIODE; NANOPORES; RECTIFICATION; MOLECULES; MECHANISM;
D O I
10.1039/b820556f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this tutorial review, recent developments in modeling and experimental studies on nanofludics were reported. Nanofluidic studies were categorized into two groups depending on the characteristic length scale. When the size of the nanochannels and pores is 5-100 nm, electrostatic interactions are dominant, and ion and fluid flow can be analyzed by continuum dynamics. Various nanofluidic devices were proposed to manipulate aqueous solutions and biomolecules at the nanoscale. The successful development of such systems has major implications for technologies focusing on water purification and processing of complex biological solutions. When the size is less than 5 nm, steric interactions and hydration affect ion and fluid flow, which is analyzed by stochastic and/or molecular dynamics.
引用
收藏
页码:901 / 911
页数:11
相关论文
共 44 条
[1]   A pH-tunable nanofluidic diode:: Electrochemical rectification in a reconstituted single ion channel [J].
Alcaraz, Antonio ;
Ramirez, Patricio ;
Garcia-Gimenez, Elena ;
Lopez, M. Lidon ;
Andrio, Andreu ;
Aguilella, Vicente M. .
JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (42) :21205-21209
[2]  
[Anonymous], 1988, Zeta Potential in Colloid Science: Principles and Applications
[3]   Computer simulations of membrane proteins [J].
Ash, WL ;
Zlomislic, MR ;
Oloo, EO ;
Tieleman, DP .
BIOCHIMICA ET BIOPHYSICA ACTA-BIOMEMBRANES, 2004, 1666 (1-2) :158-189
[4]  
Bard A.J, 2002, Student Solutions Manual to accompany Electrochemical Methods: Fundamentals and Applicaitons, V2e
[5]   A hydrophobic gating mechanism for nanopores [J].
Beckstein, O ;
Biggin, PC ;
Sansom, MSP .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (51) :12902-12905
[6]   Poisson-Nernst -Planck model of ion current rectification through a nanofluidic diode [J].
Constantin, Dragos ;
Siwy, Zuzanna S. .
PHYSICAL REVIEW E, 2007, 76 (04)
[7]   Invalidity of continuum theories of electrolytes in nanopores [J].
Corry, B ;
Kuyucak, S ;
Chung, SH .
CHEMICAL PHYSICS LETTERS, 2000, 320 (1-2) :35-41
[8]   Nanofluidic diode and bipolar transistor [J].
Daiguji, H ;
Oka, Y ;
Shirono, K .
NANO LETTERS, 2005, 5 (11) :2274-2280
[9]   Ion transport in nanofluidic channels [J].
Daiguji, H ;
Yang, PD ;
Majumdar, A .
NANO LETTERS, 2004, 4 (01) :137-142
[10]   Theoretical study on the efficiency of nanofluidic batteries [J].
Daiguji, Hirofumi ;
Oka, Yukiko ;
Adachi, Takuma ;
Shirono, Katsuhiro .
ELECTROCHEMISTRY COMMUNICATIONS, 2006, 8 (11) :1796-1800