Are the Judd-Ofelt intensity parameters sensitive enough to reflect small compositional changes in lanthanide-doped glasses?

被引：40

作者：

Binnemans, K ^{[1
]}

Gorller-Walrand, C ^{[1
]}

机构：

[1] Katholieke Univ Leuven, Dept Chem, Coordinat Chem Div, B-3001 Heverlee, Belgium

来源：

JOURNAL OF PHYSICS-CONDENSED MATTER | 1998年 / 10卷 / 10期

关键词：

D O I：

10.1088/0953-8984/10/10/002

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

Although the Omega lambda intensity parameters and especially the Omega(2) parameter can show a considerable spread for a particular lanthanide ion in different host matrices, the values of these parameters for lanthanide ions in glasses are relatively close to each other. Combined with the fact that large errors are inherent to these parameters, we emphasize that one has to be careful when interpreting or comparing intensity parameters for lanthanide ions in glasses. The analysis of a large data-set of intensity parameters reported for glasses indicates that Omega(4) congruent to Omega(6). No correlation was found between the Omega(2) parameter and the two other parameters.

引用

页码：L167 / L170

页数：4

共 17 条

[1]

ADAM JL, 1991, SPIE, V1581, P155

[2] Absorption and magnetic circular dichroism spectra of praseodymium doped fluorozirconate (ZBLAN) glass [J].

Binnemans, K ;

Verboven, D ;

GorllerWalrand, C ;

Lucas, J ;

DuhamelHenry, N ;

Adam, JL .

JOURNAL OF ALLOYS AND COMPOUNDS, 1997, 250 (1-2) :321-325

[3]

BINNEMANS K, 1998, IN PRESS J ALLOYS CO

[4] OPTICAL-PROPERTIES OF ND3+ IONS IN LITHIUM BORATE GLASSES [J].

DEVI, AR ;

JAYASANKAR, CK .

MATERIALS CHEMISTRY AND PHYSICS, 1995, 42 (02) :106-119

[5] Application of standard and modified Judd-Ofelt theories to a praseodymium-doped fluorozirconate glass [J].

Goldner, P ;

Auzel, F .

JOURNAL OF APPLIED PHYSICS, 1996, 79 (10) :7972-7977

[6]

Gorller-Walrand C, 1998, HANDB PHYSI, V25, P101, DOI 10.1016/S0168-1273(98)25006-9

[7]

Gruen D.M., 1967, ADV CHEM SER, V71, P102

[8] OPTICAL ABSORPTION INTENSITIES OF RARE-EARTH IONS [J].

JUDD, BR .

PHYSICAL REVIEW, 1962, 127 (03) :750-&

[9] SPECTROSCOPY OF A NEW LASER GARNET LU3SC2GA3O12-ND3+ - INTENSITY LUMINESCENCE CHARACTERISTICS, STIMULATED-EMISSION, AND FULL SET OF SQUARED REDUCED-MATRIX ELEMENTS VERTICAL-BAR(PARALLEL-TO-U(T)PARALLEL-TO)VERTICAL-BAR-2 FOR ND3+ IONS [J].

KAMINSKII, AA ;

BOULON, G ;

BUONCRISTIANI, M ;

DIBARTOLO, B ;

KORNIENKO, A ;

MIRONOV, V .

PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1994, 141 (02) :471-494

[10] HYPERSENSITIVE TRANSITION-PROBABILITY IN TRIS(1,3-DIPHENYL-1,3-PROPANEDIONATO)AQUOLANTHANIDES(III) [J].

KIRBY, AF ;

PALMER, RA .

INORGANIC CHEMISTRY, 1981, 20 (12) :4219-4222

← 1 2 →