Efficient synthesis of vinyl and alkyl sulfides via hydrothiolation of alkynes and electron-deficient olefins using soluble and heterogenized gold complexes catalysts

被引：99

作者：

Corma, Avelino ^{[2
]}

Gonzalez-Arellano, Camino ^{[1
,3
]}

Iglesias, Marta ^{[1
]}

Sanchez, Felix ^{[3
]}

机构：

[1] CSIC, Inst Ciencia Mat Madrid, Madrid 28049, Spain

[2] Univ Politecn Valencia, Inst Tecnol Quim, CSIC, Valencia 46022, Spain

[3] CSIC, Inst Quim Organ Gen, E-28006 Madrid, Spain

来源：

APPLIED CATALYSIS A-GENERAL | 2010年 / 375卷 / 01期

关键词：

Hydrothiolation; Alkyl sulfides; Vinyl sulfides; Heterogenized catalysts; Gold catalysts; ANTI-MARKOVNIKOV HYDROAMINATION; MICHAEL ADDITION; METAL-COMPLEXES; BOND FORMATION; C-S; THIOLS; PALLADIUM; ALKENES; VINYLARENES; GOLD(III);

D O I：

10.1016/j.apcata.2009.12.016

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Soluble and heterogenized gold complexes catalyze the hydrothiolation of alkynes and electron-deficient olefins in high yields and with high anti-Markovnikov selectivity. Moreover heterogenized catalysts could be recycled in several successive runs without any loss of activity or selectivity. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：49 / 54

页数：6

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