Transition-metal-mediated dearomatization reactions

被引：670

作者：

Pape, AR ^{[1
]}

Kaliappan, KP ^{[1
]}

Kündig, EP ^{[1
]}

机构：

[1] Univ Geneva, Dept Organ Chem, CH-1211 Geneva, Switzerland

来源：

CHEMICAL REVIEWS | 2000年 / 100卷 / 08期

关键词：

D O I：

10.1021/cr9902852

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A review of the literature covering transition-metal-mediated dearomatization chemistry is presented. It is shown that the use of chromium, manganese, and osmium provides rapid access to compounds which otherwise require long and tedious manipulations. A methodology is introduced, that can be used to synthesize complex organic products with high regio-, chemo-, stereo-, and often enantioselectivity.

引用

页码：2917 / 2940

页数：24

共 152 条

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