MoO(OiPr)4 decomposition pathways on ageing:: spontaneous and nearly quantitative transformation into Mo6O10(OiPr)12

被引：12

作者：

Kessler, VG ^{[1
]}

Shevelkov, AV

Bengtsson-Kloo, LA

机构：

[1] Moscow MV Lomonosov State Univ, Dept Inorgan Chem, Moscow 119899, Russia

[2] Univ Lund, Dept Chem, S-22100 Lund, Sweden

来源：

POLYHEDRON | 1998年 / 17卷 / 5-6期

关键词：

MoO((OPr)-Pr-i)(4); acetone; ether;

D O I：

10.1016/S0277-5387(97)00245-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Liquid samples of MoO((OPr)-Pr-i)(4) (I), kept at room temperature in complete isolation from oxygen and moisture, nearly completely solidify after approximately 2 months of storage. GLC-MS analysis of the liquid residue showed it containing approximately equal amounts of (PrOH)-Pr-i and acetone and excess of (Pr2O)-Pr-i. Multinuclear NMR (C-13, O-17 and Mo-95) investigation of this reaction in solution in toluene proved that acetone and ether elimination occur simultaneously. The solid product of the reaction was identified as Mo6O10((OPr)-Pr-i)(12) (II). (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：965 / 968

页数：4

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