Ruthenium-bisimine: A new catalytic precursor for regioselective allylic alkylation

被引：46

作者：

Renaud, JL ^{[1
]}

Bruneau, C ^{[1
]}

Demerseman, B ^{[1
]}

机构：

[1] Univ Rennes 1, Inst Chim, UMR 6509, F-35042 Rennes, France

来源：

SYNLETT | 2003年 / 03期

关键词：

regioselective allylic alkylation; ruthenium(bisimine) complex catalysed; coupling reactions;

D O I：

10.1055/s-2003-37120

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

New complexes [Cp*Ru(bisimine)Cl] are active catalysts for the regioselective alkylation of allylic carbonates by soft carbonucleophiles, in favour of the branched isomers. The catalysts can be conveniently prepared in situ from [Cp*Ru(cod)Cl] and a bulky aromatic bisimine.

引用

页码：408 / 410

页数：3

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