Statistical design of experiments as a tool for optimizing the batch conditions of Cu(II) biosorption using pecan nutshells as biosorbent.

被引:12
作者
Brasil, Jorge L. [1 ]
Vaghetti, Julio C. P. [1 ]
Royer, Betina [1 ]
dos Santos, Araci A., Jr. [1 ]
Simon, Nathalia M. [1 ]
Pavan, Flavio A. [1 ]
Dias, Silvio L. P. [1 ]
Lima, Eder C. [1 ]
机构
[1] Univ Fed Rio Grande do Sul, Inst Quim, BR-91501970 Porto Alegre, RS, Brazil
来源
QUIMICA NOVA | 2007年 / 30卷 / 03期
关键词
biosorption; statistical design of experiments; Carya illinoensis;
D O I
10.1590/S0100-40422007000300008
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In order to reduce the total number of experiments for achieving the highest amount of adsorbed Ca2+ (qmax) using pecan nutshells (Carya illinoensis) as biosorbent, a full 2(4) factorial design with two central points was carried out (mass of biosorbent- m, pH, initial metallic ion concentration- C-0, time of contact- t). In order to continue the optimization of the system, a central composite surface analysis design with two factors and five central points was carried out. The maximum amount of Cu2+ taken up by the pecan nutshells was 20 mg g(-1). These results were confirmed by determining a Cu2+ isotherm using the best conditions attained by the statistical design of experiments.
引用
收藏
页码:548 / 553
页数:6
相关论文
共 52 条
[1]   Dabco/silica sol-gel hybrid material.: The influence of the morphology on the CdCl2 adsorption capacity [J].
Arenas, LT ;
Vaghetti, JCP ;
Moro, CC ;
Lima, EC ;
Benvenutti, EV ;
Costa, TMH .
MATERIALS LETTERS, 2004, 58 (06) :895-898
[2]   Gold sorption on chitosan derivatives [J].
Arrascue, ML ;
Garcia, HM ;
Horna, O ;
Guibal, E .
HYDROMETALLURGY, 2003, 71 (1-2) :191-200
[3]   Low-cost adsorbents for heavy metals uptake from contaminated water: a review [J].
Babel, S ;
Kurniawan, TA .
JOURNAL OF HAZARDOUS MATERIALS, 2003, 97 (1-3) :219-243
[4]   A review of potentially low-cost sorbents for heavy metals [J].
Bailey, SE ;
Olin, TJ ;
Bricka, RM ;
Adrian, DD .
WATER RESEARCH, 1999, 33 (11) :2469-2479
[5]  
Barros Neto B, 2003, COMO FAZER EXPT PESQ
[6]   Biosorption of copper(II) from aqueous solutions by wheat shell [J].
Basci, N ;
Kocadagistan, E ;
Kocadagistan, B .
DESALINATION, 2004, 164 (02) :135-140
[7]   Factorial design for optimization of flow-injection preconcentration procedure for copper(II) determination in natural waters, using 2-aminomethylpyridine grafted silica gel as adsorbent and spectrophotometric detection [J].
Brasil, JL ;
Martins, LC ;
Ev, RR ;
Dupont, J ;
Dias, SLP ;
Sales, JAA ;
Airoldi, C ;
Lima, EC .
INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY, 2005, 85 (07) :475-491
[8]   Statistical design of experiments as a tool for optimizing the batch conditions to Cr(VI) biosorption on Araucaria angustifolia wastes [J].
Brasil, Jorge L. ;
Ev, Ricardo R. ;
Milcharek, Caroline D. ;
Martins, Lucas C. ;
Pavan, Flavio A. ;
dos Santos, Araci A., Jr. ;
Dias, Silvio L. P. ;
Dupont, Jairton ;
Norena, Caciano P. Zapata ;
Lima, Eder C. .
JOURNAL OF HAZARDOUS MATERIALS, 2006, 133 (1-3) :143-153
[9]  
BRITO NN, 2004, 4 FORUM ESTUDOS CONT
[10]   Potential remediation of waters contaminated with Cr(III), Cu, and Zn by sorption on the organic polymeric fraction of olive mill wastewater (polymerin) and its derivatives [J].
Capasso, R ;
Pigna, M ;
De Martino, A ;
Pucci, M ;
Sannino, F ;
Violante, A .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2004, 38 (19) :5170-5176