Bridged and unbridged substituted indenyl complexes of titanium and zirconium as catalysts for homogeneous and heterogeneous homo- and copolymerization of olefins

被引：18

作者：

Alt, HG ^{[1
]}

Weis, A ^{[1
]}

Reb, A ^{[1
]}

Ernst, R ^{[1
]}

机构：

[1] Univ Bayreuth, Lehrstuhl Anorgan Chem 2, Anorgan Chem Lab, D-95440 Bayreuth, Germany

来源：

INORGANICA CHIMICA ACTA | 2003年 / 343卷

关键词：

half-sandwich complexes; catalysis; olefin polymerization; titanium; zirconium;

D O I：

10.1016/S0020-1693(02)01240-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Bridged and unbridged indenyl half-sandwich complexes of titanium and zirconium with omega-alkenyl functions in position 2 of the indenyl ring were synthesized and characterized. After activation with methylalumoxane (MAO), these complexes were used as homogeneous and heterogeneous catalysts for the homopolymerization of ethylene and propylene and the copolymerization of ethylene and 1,7-octadiene. Due to the w-alkenyl function of the substituent, these complexes can undergo reactions with the monomeric olefin to give self-immobilization combining the advantages of homogeneous and heterogeneous catalysis. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：253 / 274

页数：22

共 39 条

[1] Effect of the nature of metallocene complexes of group IV metals on their performance in catalytic ethylene and propylene polymerization [J].

Alt, HG ;

Köppl, A .

CHEMICAL REVIEWS, 2000, 100 (04) :1205-1221

[2] Amido functionalized ansa half-sandwich dichloride complexes of titanium, zirconium and hafnium with alkyl and ω-alkenyl substituents as homogeneous and self-immobilizing catalyst precursors for ethylene polymerization [J].

Alt, HG ;

Reb, A ;

Milius, W ;

Weis, A .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 628 (02) :169-182

[3] The heterogenization of homogeneous metallocene catalysts for olefin polymerization [J].

Alt, HG .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (11) :1703-1709

[4] C2-bridged metallocene dichloride complexes of the types (C13H8-CH2CHR-C9H6-nR′n)ZrCl2 and (C13H8-CH2CHR-C13H8)MCl2 (n = 0, 1; R = H, alkenyl; R′ = alkenyl, benzyl; M = Zr, Hf) as self-immobilizing catalyst precursors for ethylene polymerization [J].

Alt, HG ;

Jung, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 580 (01) :1-16

[5] ansa-metallocene complexes of type (C13H8-SiR2-C9H6-nR′n)ZrCl2 (n = 0, 1, R = Me, Ph, alkenyl, R′ = alkyl, alkenyl):: self-immobilizing catalysts precursors for ethylene polymerization [J].

Alt, HG ;

Jung, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 562 (02) :229-253

[6] Linked amido-indenyl complexes of titanium [J].

Amor, F ;

Okuda, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 520 (1-2) :245-248

[7]

[Anonymous], ANGEW CHEM

[8]

Britovsek GJP, 1999, ANGEW CHEM INT EDIT, V38, P428, DOI 10.1002/(SICI)1521-3773(19990215)38:4<428::AID-ANIE428>3.0.CO

[9]

2-3

[10]

CANICH JAM, 1993, CHEM ABSTR, V118, P81615

← 1 2 3 4 →