New route to organoaluminium sulfides:: synthesis of (MesAlS)2 (Mes = -C6H2Bu3t-2,4,6) and its dimethyl sulfoxide adduct [Mes*AlS(OSMe2)]2

被引：29

作者：

Wehmschulte, RJ ^{[1
]}

Power, PP ^{[1
]}

机构：

[1] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 03期

关键词：

D O I：

10.1039/a707142f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of the alane (Mes*AlH2)(2) (Mes* = -C6H2Bu3t-2,4,6) with S(SiMe3)(2) in refluxing toluene affords the novel organoaluminium sulfide (Mes*AlS)(2) 1 which has a previously unobserved dimeric structure; treatment of 1 with 2 equiv, of Me2SO furnishes the complex [Mes*AlS(OSMe2)](2) 2 in which a dimeric configuration is retained, and which shows weak intermolecular interactions between neighboring dimers.

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页码：335 / 336

页数：2

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