ISOLATION OF THE 1ST GALLIUM HYDROSULPHIDO COMPLEX AND ITS FACILE CONVERSION TO A GA4S4 CUBANE - X-RAY STRUCTURES OF [(BUT)2GA(MU-SH)]2 AND [(BUT)GAS]4

被引：71

作者：

POWER, MB ^{[1
]}

BARRON, AR ^{[1
]}

机构：

[1] HARVARD UNIV,DEPT CHEM,CAMBRIDGE,MA 02138

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 18期

关键词：

D O I：

10.1039/c39910001315

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of (Bu(t))3 Ga with an excess of H2S in pentane at ambient temperature results in the formation of the hydrosulphido bridged dimer [((Bu(t))2Ga(mu-SH)2, 1, which upon mil thermolysis is converted to the cubic tetramer [(Bu(t))GaS]4 2. Compounds 1 and 2 have been characterized by IR, NMR and mass spectroscopy and their molecular structures have been determined by X-ray crystallography.

引用

页码：1315 / 1317

页数：3

共 19 条

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