Cis-dioxomolybdenum(VI) complexes as new catalysts for the Meyer-Schuster rearrangement.

被引：68

作者：

Lorber, CY ^{[1
]}

Osborn, JA ^{[1
]}

机构：

[1] UNIV STRASBOURG 1,INST LE BEL,LAB CHIM MET TRANSIT & CATALYSE,CNRS,F-67000 STRASBOURG,FRANCE

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 06期

关键词：

D O I：

10.1016/0040-4039(95)02324-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We describe a new catalytic system for the isomerisation of propargylic alcohols into alpha,beta-ethylenic carbonyl derivatives (Meyer-Schuster rearrangement)(1), based on the combination of dioxomolybdenum(VI) catalysts and sulfoxides.

引用

页码：853 / 856

页数：4

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