Nonradiative relaxation from 3MLCT excited states of Re(I), Ru(II) and Os(II) complexes:: Franck-Condon factors from quantum chemical calculations

被引：3

作者：

Baranovski, VI ^{[1
]}

Lubimova, OO ^{[1
]}

机构：

[1] St Petersburg Univ, Fac Chem, St Petersburg 198504, Russia

来源：

CHEMICAL PHYSICS LETTERS | 2003年 / 370卷 / 5-6期

关键词：

D O I：

10.1016/S0009-2614(03)00175-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Franck-Condon factors for nonradiative transitions from (MLCT)-M-3 excited states in 16 complexes of Re(I), Ru(II) and Os(II) with alpha-diimine ligands were estimated using ligand's geometry, vibrational frequencies and normal modes obtained by ab initio quantum chemical calculations. The linear correlation was obtained between logarithms of experimental constants of nonradiative transitions and theoretical Franck-Condon factors. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：636 / 640

页数：5

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