Mechanochemical synthesis of nanocrystalline TiO2 from liquid TiCl4

被引：39

作者：

Billik, P. ^{[1
]}

Plesch, G. ^{[1
]}

机构：

[1] Comenius Univ, Fac Nat Sci, Dept Inorgan Chem, Bratislava 84215, Slovakia

来源：

SCRIPTA MATERIALIA | 2007年 / 56卷 / 11期

关键词：

mechanical milling; powder processing; X-ray diffraction (XRD); nanocrystalline materials; TiO2;

D O I：

10.1016/j.scriptamat.2007.01.048

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The synthesis of TiO2 by soft mechanochemical reaction and subsequent annealing of the products was studied. In the first series liquid TiCl4 and (NH4)(2)CO3 powder were used as reactants, while in the second one TiCl4 and (NH4)(2)CO3 were again used but with Na2SO4 center dot 10H(2)O and Na2SO4 employed as additives. The synthesis was almost complete after 5 min of milling. The NH4Cl by-product was removed by low-temperature heating. Annealing at 230-650 degrees C led to anatase TiO2 with a crystallite size calculated by X-ray diffraction to be in the range 10-50 nm. (C) 2007 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

引用

页码：979 / 982

页数：4

共 24 条

[1]

Avvakumov E. G., 2004, CHEM SUSTAINABLE DEV, V12, P287

[2] Features of the procedures to obtain ultrafine zirconium dioxide by mechanochemical method [J].

Avvakumov, EG ;

Karakchiev, LG .

JOURNAL OF MATERIALS SCIENCE, 2004, 39 (16-17) :5181-5184

[3]

Avvakumov EG., 2001, SOFT MECHANOCHEMICAL

[4] Mechanochemical route for sulphide nanoparticles preparation [J].

Baláz, P ;

Boldizárová, E ;

Godocíková, E ;

Briacin, J .

MATERIALS LETTERS, 2003, 57 (9-10) :1585-1589

[5] Kinetics and mechanisms of phase transformations induced by ball-milling in anatase TiO2 [J].

Bégin-Colin, S ;

Girot, T ;

Le Caër, G ;

Mocellin, A .

JOURNAL OF SOLID STATE CHEMISTRY, 2000, 149 (01) :41-48

[6] Mechanochemical synthesis of anatase and rutile nanopowders from TiOSO4 [J].

Billik, P. ;

Plesch, G. .

MATERIALS LETTERS, 2007, 61 (4-5) :1183-1186

[7] Effect of TiO2 acidic pre-treatment on the photocatalytic properties for phenol degradation [J].

Colón, G ;

Sánchez-España, JM ;

Hidalgo, MC ;

Navío, JA .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2006, 179 (1-2) :20-27

[8] Photocatalytic behaviour of sulphated TiO2 for phenol degradation [J].

Colón, G ;

Hidalgo, MC ;

Navío, JA .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2003, 45 (01) :39-50

[9] Mechanochemical synthesis of ultrafine ZrO2 powder [J].

Ding, J ;

Tsuzuki, T ;

McCormick, PG .

NANOSTRUCTURED MATERIALS, 1997, 8 (01) :75-81

[10] EFFECTS OF MECHANICAL ACTIVATION OF INORGANIC GELS ON THEIR THERMAL-BEHAVIOR .1. CRYSTALLIZATION PROCESS OF TITANIA GELS [J].

ISOBE, T ;

SENNA, M .

JOURNAL OF SOLID STATE CHEMISTRY, 1991, 93 (02) :358-367

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