New salt binders whose ligands were composed of four aromatic sp2 nitrogens and purely based on a cavitand

被引：7

作者：

Yoon, J

Paek, K ^{[1
]}

机构：

[1] Soong Sil Univ, Dept Chem, Seoul 156743, South Korea

[2] Ctr Biofunct Mol, Pohang 790600, South Korea

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 20期

关键词：

D O I：

10.1016/S0040-4039(98)00448-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

New salt binders whose ligands were composed of four aromatic sp? nitrogens and purely based on a cavitand were efficiently synthesized and characterized. Imidazolylcavitand 3 showed high affinity for picrate salts (-Delta G(degrees)=7.0 similar to 11.0 kcal mol(-1)) and pyrazolylcavitand 4 showed unusual high selectivity for silver picrate. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：3161 / 3164

页数：4

共 16 条

[11]

KIM K, 1993, B KOREAN CHEM SOC, V14, P658

[12] HOST GUEST COMPLEXATION .51. CYANOSPHERANDS, A NEW TYPE OF SALT BINDER [J].