A cyano-bridged molecule-based magnet containing manganese(III) Schiff base and octacyanotungstate(V) building blocks

被引：53

作者：

Kou, HZ ^{[1
]}

Ni, ZH ^{[1
]}

Zhou, BC ^{[1
]}

Wang, RJ ^{[1
]}

机构：

[1] Tsing Hua Univ, Dept Chem, Beijing 100084, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 10期

基金：

中国国家自然科学基金;

关键词：

crystal structure; manganese complex; Tungsten complex; Schiff base; cyanide bridging; magnetic property;

D O I：

10.1016/j.inoche.2004.08.017

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A hetero-bimetallic complex K[Mn(acacen)](2)[W(CN)(8)] (.) 2H(2)O (acacen(2-) = dianion of N,N'-ethylenebis(acetylacetonylideneaminato)) consists of two-dimensional gridlike {[Mn(acacen)](2)[W(CN)(8)]}(-) layers that are linked by K+ ions giving rise to a three-dimensional network. Ferromagnetic Mn(III)-W(V) coupling and magnetic ordering at 18.0 K (T-c) have been observed in the complex. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：1150 / 1153

页数：4

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