Reactions of [IrCl(Bu-2(t)PH)(3)] with [M-3(CO)(12)](M=Fe,Ru): Synthesis and X-ray crystal structures of the metal clusters [Ru-3(CO)(8)(mu-H)(2)(mu(3)-PBut)(Bu-2(t)PH)] and [Ru3Ir(CO)(7)(mu-H)(2)(mu-PBu2t)(2)(Bu-2(t)PH)(mu(3)-Cl)]

被引：15

作者：

Bottcher, HC

Graf, M

Merzweiler, K

机构：

[1] Inst. für Anorganische Chemie, Martin-Luther-Univ. Halle-Wittenberg, D-06120 Halle/Saale

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 531卷 / 1-2期

关键词：

ruthenium; iridium; carbonyl; cluster; phosphido-bridged; crystal structure;

D O I：

10.1016/S0022-328X(96)06685-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of [IrCl((Bu2PH)-P-t)(3)] (1) with the metal carbonyls [M-3(CO)(12)] (M = Fe, Ru) in refluxing toluene have been investigated. By using [Ru-3(CO)(12)] the metal cluster [Ru-3(CO)(8)(mu-H)(2)(mu(3)-PBut)((Bu2PH)-P-t)] (2) and the butterfly configured heterometallic cluster [Ru3Ir(CO)(7)(mu-H)(2)(mu-PBu2t)(2)((Bu2PH)-P-t)(mu(3)-Cl)] (3) were obtained. On the contrary, the reaction of 1 with [Fe-3(CO)(12)] leads under cluster degradation beside the mononuclear complex [Fe(CO)(4)((Bu2PH)-P-t)] (5) to the known compound [FeIr(mu-CO)(CO)(4)(mu-PBu2t)((Bu2PH)-P-t)] (4) in good yields. The molecular structures of 2 and 3 have been determined by single crystal X-ray studies.

引用

收藏

页码：107 / 113

页数：7

相关论文

共 19 条

[1]

ADAMS RD, 1995, COMPREHENSIVE ORGANO, V10, P1, DOI DOI 10.1016/B978-008046519-7.00085-X

[2] REVERSIBLE METAL-METAL BOND-CLEAVAGE ACCOMPANIED BY THE FACILE REVERSIBLE ADDITION OF H-2 TO A RU-3 CLUSTER - SYNTHESIS AND X-RAY STRUCTURES OF RU3(CO)8(MU-H)2(MU-T-BU2P)2 AND RU3(CO)8(MU-H)2(H)2(MU-T-BU2P)2 [J].

ARIF, AM ;

BRIGHT, TA ;

JONES, RA ;

NUNN, CM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (20) :6894-6895

[3] SYNTHESIS OF PHOSPHIDO-BRIDGED MULTINUCLEAR COMPLEXES VIA A MONONUCLEAR RHODIUM(I) COMPOUND - X-RAY STRUCTURES OF RH3H(COD)2(MU-CO)2(MU-P(TERT-BU)2)2 AND [FE(CO3)](MU-CO)(MU-P(TERT-BU)2)[RH(CO)(HP(TERT-BU)2)] (COD=1,5-CYCLOOCTADIENE) [J].

ARIF, AM ;

HEATON, DE ;

JONES, RA .

POLYHEDRON, 1991, 10 (06) :543-551

[4] Iridium complexes with secondary phosphines: Synthesis and X-ray crystal structure of [IrCl(Bu(2)(t)PH)(3)] [J].

Bottcher, HC ;

Graf, M ;

Merzweiler, K .

POLYHEDRON, 1997, 16 (02) :341-343

[5]

BOTTCHER HC, IN PRESS J ORGANOMET

[6] SYNTHESES, STRUCTURES, REACTIONS, AND VIBRATIONAL SPECTRA OF COMPLEXES CONTAINING OSMIUM-GOLD BONDS - TRINUCLEAR OSMIUM AND RELATED COMPLEXES [J].

BRADFORD, CW ;

VANBRONS.W ;

CLARK, RJH .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1970, (17) :2889-&

[7] CLUSTER CHEMISTRY .51. REACTIONS OF SOME SUBSTITUTED RUTHENIUM AND OSMIUM CLUSTER CARBONYLS WITH DIHYDROGEN - X-RAY CRYSTAL-STRUCTURES OF RU3(MU-H)2(MU3-PPH)(CO)8(PMEPH2), RU4(MU-H)4(MU-DPPM)(CO)10, RU4(MU-H)3(MU-3-PPHCH2PPH2)(CO)10 AND OS3(MU-H)2(MU-DPPM)(CO)8 [J].

BRUCE, MI ;

HORN, E ;

SHAWKATALY, OB ;

SNOW, MR ;

TIEKINK, ERT ;

WILLIAMS, ML .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 316 (1-2) :187-211

[8] CONDENSATION AS WELL AS TRINUCLEAR PRODUCTS FROM THE REACTION OF TRIRUTHENIUM DODECACARBONYL WITH DIPHENYLPHOSPHINE [J].

BULLOCK, LM ;

FIELD, JS ;

HAINES, RJ ;

MINSHALL, E ;

MOORE, MH ;

MULLA, F ;

SMIT, DN ;

STEER, LM .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 381 (03) :429-456

[9]

CARTY AJ, 1987, PHOSPHORUS 31 NMR SP, P559

[10] SYNTHESIS AND LIGAND-EXCHANGE REACTIONS OF HETEROBIMETALLIC DI-TERT-BUTYLPHOSPHIDO-BRIDGED COMPLEXES OF CR-CO, CR-RH, AND FE-CO - X-RAY CRYSTAL-STRUCTURES OF (CO)5CR(MU-TERT-BU2P)RH(1,5-CYCLOOCTADIENE)(CR-RH), (CO)3(PME3)CR(MU-TERT-BU2P)(MU-CO)CO(PME3)(CO)(CR-CO), AND (CO)3(PME3)FE(MU-TERT-BU2P)CO(CO)2(PME3)(FE-CO)TR [J].

CHANDLER, DJ ;

JONES, RA ;

STUART, AL ;

WRIGHT, TC .

ORGANOMETALLICS, 1984, 3 (12) :1830-1838