A unique coordination of SiH4:: Isolation, characterization, and theoretical study of (PR3)2H2Ru(SiH4)RuH2(PR3)2

被引:69
作者
Atheaux, I
Donnadieu, B
Rodriguez, V
Sabo-Etienne, S
Chaudret, B
Hussein, K
Barthelat, JC
机构
[1] CNRS, Chim Coordinat Lab, F-31077 Toulouse 04, France
[2] Univ Toulouse 3, UMR 5626, IRSAMC, Phys Quant Lab, F-31062 Toulouse 4, France
关键词
D O I
10.1021/ja000223p
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
引用
收藏
页码:5664 / 5665
页数:2
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共 26 条
  • [1] EXTENDED GAUSSIAN-TYPE VALENCE BASIS-SETS FOR CALCULATIONS INVOLVING NON-EMPIRICAL CORE PSEUDOPOTENTIALS
    BOUTEILLER, Y
    MIJOULE, C
    NIZAM, M
    BARTHELAT, JC
    DAUDEY, JP
    PELISSIER, M
    SILVI, B
    [J]. MOLECULAR PHYSICS, 1988, 65 (02) : 295 - 312
  • [2] Reactions of hydrosilanes with transition-metal complexes: Formation of stable transition-metal silyl compounds
    Corey, JY
    Braddock-Wilking, J
    [J]. CHEMICAL REVIEWS, 1999, 99 (01) : 175 - 292
  • [3] CRABTREE RH, 1993, ANGEW CHEM INT EDIT, V32, P789, DOI 10.1002/anie.199307891
  • [4] Curtis M.D., 1981, Adv. Organomet. Chem, V19, P213
  • [5] Ruthenium complexes containing two Ru-(η2-Si-H) bonds:: Synthesis, spectroscopic properties, structural data, theoretical calculations, and reactivity studies
    Delpech, F
    Sabo-Etienne, S
    Daran, JC
    Chaudret, B
    Hussein, K
    Marsden, CJ
    Barthelat, JC
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (28) : 6668 - 6682
  • [6] Synthesis and characterization of chelating bis(silane) complexes [RuH2{(eta(2)-HSiMe(2))(2)X}(PCy(3))(2)] (X=C6H4, O) containing two Ru-(Pt-Si-H) bonds
    Delpech, F
    SaboEtienne, S
    Chaudret, B
    Daran, JC
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (13) : 3167 - 3168
  • [7] Synthesis and study of rutheniun silylene complexes of the type [(η5-C5Me5)(Me3P)2Ru=SiX2]+ (X = thiolate, Me, and Ph)
    Grumbine, SK
    Mitchell, GP
    Straus, DA
    Tilley, TD
    Rheingold, AL
    [J]. ORGANOMETALLICS, 1998, 17 (26) : 5607 - 5619
  • [8] BASE-FREE SILYLENE COMPLEXES WITHOUT PI-DONOR STABILIZATION - MOLECULAR-STRUCTURE OF [CP-ASTERISK(PME3)(2)RU=SIME2][B(C6F5)(4)]
    GRUMBINE, SK
    TILLEY, TD
    ARNOLD, FP
    RHEINGOLD, AL
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (12) : 5495 - 5496
  • [9] Synthesis and structural characterization of Cp2Ti(SiH3)(PMe3)
    Hao, LJ
    Lebuis, AM
    Harrod, JF
    [J]. CHEMICAL COMMUNICATIONS, 1998, (10) : 1089 - 1090
  • [10] Preparation and characterization of titanocene silyl hydrides [Cp2Ti(mu-HSiH2)](2) and [Cp2Ti(mu-HSiH2)(mu-H)TiCp2]
    Hao, LJ
    Lebuis, AM
    Harrod, JF
    Samuel, E
    [J]. CHEMICAL COMMUNICATIONS, 1997, (22) : 2193 - 2194