Catalytic selective cleavage of a strong C-C single bond by rhodium in solution

被引：100

作者：

Liou, SY ^{[1
]}

van der Boom, ME ^{[1
]}

Milstein, D ^{[1
]}

机构：

[1] Weizmann Inst Sci, Dept Organ Chem, IL-76100 Rehovot, Israel

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 06期

关键词：

D O I：

10.1039/a800537k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of [RhCl(C8H14)(2)](2) With an excess of the diphosphine 1,3-bis(diisopropylphosphinomethylene)me 1 in dioxane under mild H-2 pressure (25 psi) or with an excess of HSi(OEt)(3) results in catalytic selective cleavage of a strong C-C single bond.

引用

页码：687 / 688

页数：2

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